ORIGINAL RESEARCH
Mechanism of Cd Adsorption by Sulphur
Modified Biochar and Its Application
in Cd-Contaminated Soil
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1
College of Environmental Science and Engineering, Yangzhou University, Yangzhou, Jiangsu 225127, China
2
Jiangsu organic solid waste resources Collaborative Innovation Center, Nanjing, Jiangsu 210095
Submission date: 2023-12-18
Final revision date: 2024-01-16
Acceptance date: 2024-01-30
Online publication date: 2024-04-22
Corresponding author
Xiaobing Wang
College of Environmental Science and Engineering, Yangzhou University, Yangzhou, Jiangsu 225127, China
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ABSTRACT
Soil heavy metal pollution presents a significant environmental challenge globally, with cadmium (Cd) pollution
being highly severe and posing risks to both soil ecological security and human health. Biochar offers advantages
such as reduced costs, stable chemical properties, a micro-porous structure, and an expansive, specific surface
area that aids in the fixation of heavy metals in soil. However, there has been little research on the adsorption
mechanism of sulfur-modified biochar. Indigenous woody peat (BC) was used as a biochar substrate to evaluate
the immobilization effectiveness of sulfur-modified woody peat (SBC) in Cd-contaminated soil in terms of
cadmium and to determine the adsorption mechanism. Electron microscopy (SEM) and energy dispersive
spectroscopy (EDS) showed that the S element was loaded on the surface of woody peat materials. X-ray
photoelectron spectroscopy (XPS) analysis indicated that Cd in woody peat biochar is adsorbed mainly through
the formation of Cd(OH)2 and CdCO3 precipitates. Additionally, SBC facilitated the interaction between Cd
and organic sulfur, leading to the formation of more stable CdS and CdHS+ that were not easily dissolved or
oxidized. The study also examined the adsorption mechanism. The results indicated that the material adhered
to the second-order kinetic adsorption model. SBC had a greater capacity than BC to adsorb Cd, approximately
six times greater. The soil culture experiment yielded varying effects with the addition of SBC and BC, notably
on the soil pH and available Cd content. Adding 1% SBC resulted in a 12.5% increase in soil pH to a level of
7.52. After a 1% SBC treatment, the availability of Cd in the soil reduced significantly, with only 4.01 mg/kg
found, which was significantly different from the control (CK) treatment (P < 0.05). These results suggest that
SBC has promising potential for pollutant remediation applications.