ORIGINAL RESEARCH
Toxicity of Bromate Ions in Drinking Water
and its Determination Using Ion Chromatography
with Post Column Derivatisation
drinking quality.
R. Michalski*
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Institute of Environmental Engineering of Polish Academy of Science,
Curie-Skłodowskiej 34, 41-819 Zabrze, Poland
Pol. J. Environ. Stud. 2003;12(6):727-734
KEYWORDS
ABSTRACT
Disinfection of drinking water is usually carried out by chlorination. This is a well-known and effective
technology which has many advantages. However, during this process dangerous by-products such as
trihalomethanes, as well as chlorate and chlorite are formed.
The disinfection of bromide-containing source waters with ozone results in the production of bromate
ions (BrO3
-), which are formed as a result of a series of complex reactions between ozone and bromide ions
present in water. Bromates are possible human carcinogens. For these reasons trace analysis of bromate and
other oxyhalides by-products in waters has received considerable attention in recent years.
This article describes the determination of bromate in drinking water by IC with post column derivatisation
using NaBr/NaNO2 and UV detection. The direct method allows the determination of bromate at low
ěg/dm3 levels and sample pretreatment is not necessary.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.