ORIGINAL RESEARCH
Polyethyleneimine-Modified Garden Waste Biochar: Preparation and Its Application for Aqueous Cr(Ⅵ) Adsorption
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1
School of Water Conservancy, North China University of Water Resources and Electric Power, Zhengzhou 450046, PR China
 
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Henan Key Laboratory of Water Resources Conservation and Intensive Utilization in the Yellow River Basin, Zhengzhou, 450046, PR China
 
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School of Environmental and Municipal Engineering, North China University of Water Resources and Electric Power, Zhengzhou, 450046, PR China
 
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Henan Vocational College of Water Conservancy and Environment, Zhengzhou 450008, PR China
 
 
Submission date: 2023-09-25
 
 
Final revision date: 2023-12-08
 
 
Acceptance date: 2024-05-12
 
 
Online publication date: 2025-05-05
 
 
Publication date: 2025-06-06
 
 
Corresponding author
Jingxi Tie   

North China University of Water Resources and Electric Power, No.36 North ring road, 450011, zhengzhou, China
 
 
Pol. J. Environ. Stud. 2025;34(4):4833-4842
 
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ABSTRACT
Garden Waste (GW) and Polyethyleneimine were used as source materials to create polyethyleneimine-modified garden waste biochar (PGWBC). The composite was employed as an adsorbent in both static and dynamic Cr(VI) adsorption experiments after being evaluated using N2 adsorption-desorption and Fourier transform infrared spectroscopy. The material characterization results indicated that PGWBC was a mesoporous material that contained mainly narrow slit mesopores. The static adsorption data indicated that Cr(VI) adsorption by PGWBC was a pH-dependent process, a rise in pH from 2 to 9 resulting in a decrease in Cr(VI) adsorption from 44.6 mg/g to 3.8 mg/g. The adsorption process was endothermic and spontaneous, as characterized by the pseudo-second-order model and the Langmuir equation, the maximum Cr(Ⅵ) uptake was 56.1 mg/g in 308 K. The dynamic adsorption revealed that increasing the flow rate impaired Cr(VI) adsorption, and the Thomas model was more suited to represent Cr(VI) adsorption by PGWBC than the Yoon-Nelson model.
eISSN:2083-5906
ISSN:1230-1485
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