ORIGINAL RESEARCH
Removal of Formaldehyde from Synthetic
Wastewater Using Natural
and Modified Zeolites
Dainius Paliulis
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Department of Environmental Protection, Vilnius Gediminas Technical University,
Saulėtekio al. 11, LT-10223 Vilnius, Lithuania
Submission date: 2015-10-13
Final revision date: 2015-11-09
Acceptance date: 2015-11-24
Publication date: 2016-01-25
Pol. J. Environ. Stud. 2016;25(1):251-257
KEYWORDS
ABSTRACT
Chemically modified and natural zeolite consisting of clinoptilolite and mordenite minerals (Sokirnica
Mine, Ukraine) was selected for testing the adsorption ability of formaldehyde. Modified zeolite was produced
from natural zeolite by chemical activation with sulphuric acid (H2SO4) 2M at 95-98°C for six hours.
Synthetic wastewater was prepared by adding formaldehyde at concentrations equal to or higher than the
maximum allowable concentration (MAC) values: 1 MAC = 2 mg/l, 2 MAC = 4 mg/l, 3 MAC = 6 mg/l, 5
MAC = 10 mg/l, and 10 MAC = 20 mg/l. The effects of adsorption time (5 min, 10 min, 30 min, 60 min,
3 h, 5 h, 8 h, and 12 h) were examined for the selected formaldehyde concentrations. Adsorption efficiency,
adsorption capacity, and iodine numbers were evaluated for the selected adsorbents. The positive effect
of natural zeolite chemical modification was obtained in the range of 5.4 to 24.0%, with an average value
of 9.2 %. Iodine number was selected as a parameter for natural zeolite chemical modification with 2M
sulphuric acid evaluation. The iodine number before sorption was 154.3 mg∙g-1 and after modification was
164.5 mg∙g-1.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
CITATIONS (23):
1.
Removal of organic pollutants from produced water by batch adsorption treatment
Eman Hashim Khader, Thamer Jassim Mohammed, Nourollah Mirghaffari, Ali Dawood Salman, Tatjána Juzsakova, Thamer Adnan Abdullah
Clean Technologies and Environmental Policy
2.
Date seed activated carbon decorated with CaO and Fe3O4 nanoparticles as a reusable sorbent for removal of formaldehyde
Hossein Khaleghi, Hossein Esmaeili, Neamatollah Jaafarzadeh, Bahman Ramavandi
Korean Journal of Chemical Engineering
3.
Effect of different defects on the competitive adsorption of formaldehyde and water on the surface of carbon materials: Density functional theory study
Zhonghua Wang, Zekun Sun, Haiqian Zhao, Jun Li, Xing Zhang, Jiuyang Jia, Kaibo An, Ziyu Tang, Mingqi He, Zhibin Qu
Science of The Total Environment
4.
Effects of adding mineral adsorbents to porous concrete for enhancing the quality performance of urban runoff systems
Sayed-Farhad Mousavi, Hojat Karami, Saeed Farzin, Ehsan Teymouri
World Journal of Engineering
5.
Evaluation of Carbon Nanotubes and Quartz Sand for the Removal of Formaldehyde–(2,4-Dinitrophenylhydrazine) from Aqueous Solutions
Maria P. Georgopoulou, Constantinos V. Chrysikopoulos
Industrial & Engineering Chemistry Research
6.
Photocatalysts - Applications and Attributes
Florica Manea, Corina Orha
7.
Review of Adsorption Studies for Contaminant Removal from Wastewater Using Molecular Simulation
Noor e Hira, Serene Sow Mun Lock, Noor Fazliani Shoparwe, Irene Sow Mei Lock, Lam Ghai Lim, Chung Loong Yiin, Yi Herng Chan, Muhammad Hassam
Sustainability
8.
Modification of the Zeolite Heulandite with N-(3-Triethoxysilylpropyl)guanidines Offers an Effective Approach to Enhancing Its Adsorption Capacity for Heavy Metal Ions
Sergey N. Adamovich, Arailym M. Nalibayeva, Yerlan N. Abdikalykov, Mirgul Zh. Turmukhanova, Elena G. Filatova, Alexandr D. Chugunov, Igor A. Ushakov, Elizaveta N. Oborina, Igor B. Rozentsveig, Francis Verpoort
International Journal of Molecular Sciences
9.
Newly isolated formaldehyde degrading Bacillus cereus from effluent of SIPCOT industrial area: identification and process parameter studies
P. Ezhilkumar, V.M. Sivakumar, M. Thirumarimurugan
Desalination and Water Treatment
10.
The effect of oxygen-containing functional groups on formaldehyde adsorption in solution on carbon surface: A density functional theory study
Xue Yang, Haiqian Zhao, Zhibin Qu, Mingqi He, Ziyu Tang, Shiwei Lai, Zhonghua Wang
Journal of Environmental Chemical Engineering
11.
Exploring ionic liquids for formaldehyde separation via computational COSMO-RS screening
Huma Warsi Khan, Amal AM Elgharbawy, Mansoor Ul Hasan Shah, Berihun Mamo Negash, Mohd Kaif Khan, Kashif Khan, Hesam Kamyab, Mohammad Yusuf
Chemical Engineering Research and Design
12.
Synthesis of zeolite P from sewage sludge ash
Jolanta Latosińska, M. Dudek, W. Suwała, S. Łopata, J. Leszczyński
E3S Web of Conferences
13.
Iron slag pervious concrete for reducing urban runoff contamination
Ehsan Teymouri, Kwong Soon Wong, Nurul Noraziemah Mohd Pauzi
Journal of Building Engineering
14.
Equilibrium Isotherms of Formaldehyde Elimination from the Aqueous Solutions Containing Natural Adsorbents of Rice Bran and the Resulting Ashes
Marzieh Bagheri, Mohammad Nasiri, Amirreza Talaiekhozani, Iman Abedi
Journal of Human, Environment, and Health Promotion
15.
Optimization of process parameters for photoreforming of hydrogen evolution via response surface methodology (RSM): A study using Carbon@exfoliated g–C3N4
Thurga Devi Munusamy, Sim Yee Chin, Md.Maksudur Rahman Khan
Chemical Engineering Research and Design
16.
Cotransport of titanium dioxide nanoparticles and formaldehyde in saturated and unsaturated columns packed with quartz sand
Constantinos V. Chrysikopoulos, Theodosia V. Fountouli
Vadose Zone Journal
17.
Interaction of Titanium Dioxide with Formaldehyde in the Presence of Quartz Sand under Static and Dynamic Conditions
Anthi S. Stefanarou, Constantinos V. Chrysikopoulos
Water
18.
Treatment and Recovery of High-Value Elements from Produced Water
Michael Angelo Miranda, Anirban Ghosh, Ghader Mahmodi, Songpei Xie, Madelyn Shaw, Seokjhin Kim, Mark J. Krzmarzick, David J. Lampert, Clint P. Aichele
Water
19.
Adsorption of formaldehyde from aqueous solution using activated carbon prepared from Hibiscus rosa-sinensis
Maryam Zahed, Dariush Jafari, Morteza Esfandyari
International Journal of Environmental Analytical Chemistry
20.
Developing Lignite Pervious Concrete for Application in Pedestrian Walkways and Urban Runoff Treatment
Ehsan Teymouri, Nurul Noraziemah Mohd Pauzi, Kwong Soon Wong
Iranian Journal of Science and Technology, Transactions of Civil Engineering
21.
Soy protein selectively accumulates formaldehyde
Masanori Yamada, Momoka Uchida, Tetsuya Yamada
Scientific Reports
22.
Treatment of formaldehyde wastewater by a membrane-aerated biofilm reactor (MABR): The degradation of formaldehyde in the presence of the cosubstrate methanol
Xiang Mei, Zhongwei Guo, Juan Liu, Shuqi Bi, Pengpeng Li, Yong Wang, Wentian Shen, Yang Yang, Yihan Wang, Yanyan Xiao, Xu Yang, Yang Liu, Lu Zhao, Yuting Wang, Shuang Hu
Chemical Engineering Journal
23.
Synthesis of mesoporous MFI zeolite via bacterial cellulose-derived carbon templating for fast adsorption of formaldehyde
Arnon Khamkeaw, Muenduen Phisalaphong, Bunjerd Jongsomjit, Kun-Yi Andrew Lin, Alex C.K. Yip
Journal of Hazardous Materials