About the Journal
In Memory of Professor Jerzy Radecki
Ownership and Management Statement
Editorial Office
Editorial Board
Scope
Impact Factor
Indexed by
Journal Impact Factor contributing items
Publication Frequency
Revenue Sources & Business Model
Contact
Subscription
Current issue
Online first
Instructions for Authors
Copyright & Licensing
Publication Fees
Editorial policies
Publication Policy Overview
Peer Review Policy
Research Ethics and Malpractice Policy
Plagiarism Policy
Conflict of Interest Policy
Open Access Policy
Instructions for Reviewers
Generative AI and AI-Assisted Technologies Policy
Advertising Policy
Direct Marketing & Manuscript Solicitation
Digital Archiving and Preservation Policy
CrossMark, Correction, and Retraction Policy
Archive
Publication Fees
Copyright & Licensing
Editorial policies
Publication Policy Overview
Peer Review Policy
Research Ethics and Malpractice Policy
Plagiarism Policy
Conflict of Interest Policy
Open Access Policy
Instructions for Reviewers
Generative AI and AI-Assisted Technologies Policy
Advertising Policy
Direct Marketing & Manuscript Solicitation
Digital Archiving and Preservation Policy
CrossMark, Correction, and Retraction Policy
eISSN: 2083-5906
ISSN: 1230-1485
ISSN: 1230-1485
ORIGINAL RESEARCH
Adsorption of Methylene Blue Dye by
Modified Reed Activated Carbon: Adsorption
Optimization and Adsorption Performance
1
School of Public Utilities, Jiangsu Urban and Rural Construction Vocational College, Changzhou 213247, China
2
School of Resources and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, China
Submission date: 2024-02-09
Final revision date: 2024-03-19
Acceptance date: 2024-04-18
Online publication date: 2024-09-17
Publication date: 2025-01-28
Corresponding author
Rurong Jiang
School of Public Utilities, Jiangsu Urban and Rural Construction Vocational College, China
School of Public Utilities, Jiangsu Urban and Rural Construction Vocational College, China
Pol. J. Environ. Stud. 2025;34(3):2223-2232
KEYWORDS
adsorptionoptimizationmodified reed activated carbon (M-RAC)methylene blue (MB)response surface methodology (RSM)
TOPICS
ABSTRACT
To realize the effective utilization of reed for adsorption of methylene blue (MB), modified reed activated
carbon (M-RAC) was prepared using reed as raw material and MgCl2 and FeCl3 as activators. The four
parameters of M-RAC dosage, MB concentration, adsorption time, and oscillation velocity during the
adsorption process were optimized by the response surface methodology (RSM). The adsorption performance
of M-RAC on MB under the optimal process was determined and analyzed by three different adsorption
models. The results showed that the adsorption capacity of M-RAC on MB was 436.33 mg/g when the M-RAC
dosage was 0.17 g, the MB concentration was 550 mg/L, the adsorption time was 105 min, and the oscillation
velocity was 154 r/min. The experimental data were consistent with the Langmuir model and Pseudo-secondorder
kinetics, which indicated that the adsorption process was a monolayer chemical adsorption process.
The thermodynamic study confirmed that the increase in temperature favored the adsorption of M-RAC on
MB, and the adsorption process was a spontaneous and heat-absorbing reaction. The analysis of the Fourier
transform infrared (FTIR) spectroscopy showed that the absorption peaks of hydroxyl functional groups in
the prepared M-RAC were higher, and the C-O characteristic peaks were enhanced. The results suggest that
M-RAC is a potential biochar adsorbent for effectively removing MB dye from wastewater.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
REFERENCES (35)
1.
LI S., CHEN H., LI Y., DU Z., BIN L., LI W., FU F., LI P., TANG B. Efficient removal of refractory dyestuffs from textile wastewater by composite hydrated alumina derived from waste aluminum polishing solution. Journal of Environmental Chemical Engineering, 11 (3), 109859, 2023. https://doi.org/10.1016/j.jece....
2.
SONG Y., WANG L., QIANG X., GU W., MA Z., WANG G. An overview of biological mechanisms and strategies for treating wastewater from printing and dyeing processes. Journal of Water Process Engineering, 55, 104242, 2023. https://doi.org/10.1016/j.jwpe....
3.
GEBRE MESKEL A., KWIKIMA M.M., MESHESHA B.T., HABTU N.G., NAIK S.V.C.S., VELLANKI B.P. Malachite green and methylene blue dye removal using modified bagasse fly ash: Adsorption optimization studies. Environmental Challenges, 14, 100829, 2024. https://doi.org/10.1016/j.envc....
4.
JIANG R., YAO J., YAO Y. Optimization of The Modified Soybean Straw Activated Carbon for Adsorption of Methylene Blue Dye by Response Surface Methodology. Polish Journal of Environmental Studies, 32 (5), 4073, 2023. https://doi.org/10.15244/pjoes... PMid:20445696.
5.
HASSANZADEH H., SALEM A., SALEM S. Fabrication of MgO powder through ultrasound-assisted precipitation for uptake of reactive dyes from wastewater: Change in porous structure for efficient adsorption. Inorganic Chemistry Communications, 155, 111004, 2023. https://doi.org/10.1016/j.inoc....
6.
YE H., CHEN D., LI N., XU Q., LI H., HE J., LU J. Azine-linked covalent organic framework-modified GO membrane for high-efficiency separation of aqueous dyes and salts in wastewater. Journal of Membrane Science, 655, 120546, 2022. https://doi.org/10.1016/j.mems....
7.
ELGARAHY A.M., ELWAKEEL K.Z., MOHAMMAD S.H., ELSHOUBAKY G.A. A critical review of biosorption of dyes, heavy metals and metalloids from wastewater as an efficient and green process. Cleaner Engineering and Technology, 4, 100209, 2021. https://doi.org/10.1016/j.clet....
8.
KUMAR N., PANDEY A., ROSY SHARMA Y.C. A review on sustainable mesoporous activated carbon as adsorbent for efficient removal of hazardous dyes from industrial wastewater. Journal of Water Process Engineering, 54, 104054, 2023. https://doi.org/10.1016/j.jwpe....
9.
TOMIN O., VAHALA R., YAZDANI M.R. Synthesis and efficiency comparison of reed straw-based biochar as a mesoporous adsorbent for ionic dyes removal. Heliyon, 10 (2), e24722, 2024. https://doi.org/10.1016/j.heli... PMid:38298730 PMCid:PMC10828687.
10.
GAO Y., ZHANG J., CHEN C., DU Y., TENG G., WU Z. Functional biochar fabricated from waste red mud and corn straw in China for acidic dye wastewater treatment. Journal of Cleaner Production, 320, 128887, 2021. https://doi.org/10.1016/j.jcle....
11.
WANG H., XU J., LIU X., SHENG L. Preparation of straw activated carbon and its application in wastewater treatment: A review. Journal of Cleaner Production, 283, 124671, 2021. https://doi.org/10.1016/j.jcle....
12.
QU F., YU J., DU S., LI Y., LV X., NING K., WU H., MENG L. Influences of anthropogenic cultivation on C, N and P stoichiometry of reed-dominated coastal wetlands in the Yellow River Delta. Geoderma, 235-236, 227, 2014. https://doi.org/10.1016/j.geod....
13.
BOUBAKER H., BEN ARFI R., MOUGIN K., VAULOT C., HAJJAR S., KUNNEMAN P., SCHRODJ G., GHORBAL A. New optimization approach for successive cationic and anionic dyes uptake using reed-based beads. Journal of Cleaner Production, 307, 127218, 2021. https://doi.org/10.1016/j.jcle....
14.
Di FIDIO N., LICURSI D., PUCCINI M., VITOLO S., RASPOLLI GALLETTI A.M. Closing a biorefinery cycle of giant reed through the production of microporous and reusable activated carbon for CO2 adsorption. Journal of Cleaner Production, 428, 139359, 2023. https://doi.org/10.1016/j.jcle....
15.
ZHOU L., YU Q., CUI Y., XIE F., LI W., LI Y., CHEN M. Adsorption properties of activated carbon from reed with a high adsorption capacity. Ecological Engineering, 102, 443, 2017. https://doi.org/10.1016/j.ecol....
16.
KAROUI S., BEN ARFI R., MOUGIN K., GHORBAL A., ASSADI A.A., AMRANE A. Synthesis of novel biocomposite powder for simultaneous removal of hazardous ciprofloxacin and methylene blue: Central composite design, kinetic and isotherm studies using Brouers-Sotolongo family models. Journal of Hazardous Materials, 387, 121675, 2020. https://doi.org/10.1016/j.jhaz... PMid:31767503.
17.
WANG Z., NIE Q., LEI Z., ZHANG Z., SHIMIZU K., YUAN T. Enhanced Pb(II) removal from wastewater by co-pyrolysis biochar derived from sewage sludge and calcium sulfate: Performance evaluation and quantitative mechanism analysis. Separation and Purification Technology, 329, 125124, 2024. https://doi.org/10.1016/j.sepp....
18.
SUN M., WANG X., XIONG R., CHEN X., ZHAI L., WANG S. High-performance biochar-loaded MgAl-layered double oxide adsorbents derived from sewage sludge towards nanoplastics removal: Mechanism elucidation and QSAR modeling. Science of the Total Environment, 901, 165971, 2023. https://doi.org/10.1016/j.scit... PMid:37532050.
19.
HOU J., HUANG L., YANG Z.M. Adsorption of ammonium on biochar prepared from giant reed. Environmental Science and Pollution Research, 23 (19), 19107, 2016. https://doi.org/10.1007/s11356... PMid:27344654.
20.
CHENG S., MENG W., XING B. Efficient removal of heavy metals from aqueous solutions by Mg/Fe bimetallic oxide-modified biochar: Experiments and DFT investigations. Journal of Cleaner Production, 403, 136821, 2023. https://doi.org/10.1016/j.jcle....
21.
MOED N.M., KU Y. Regeneration of As(V) loaded granular activated carbon through desorption in FeCl3, CaCl2 and MgCl2 aqueous solutions. Water Science and Technology, 86 (5), 1253, 2022. https://doi.org/10.2166/wst.20... PMid:36358059.
22.
LIU L. A comprehensive model of adsorption of resorcinol in rotating packed bed: Theoretical, isotherm, kinetics and thermodynamics. Journal of Environmental Chemical Engineering, 11 (5), 111041, 2023. https://doi.org/10.1016/j.jece....
23.
MOKHTAR A., ABDELKRIM S., BOUKOUSSA B., HACHEMAOUI M., DJELAD A., SASSI M., ABBOUD M. Elimination of toxic azo dye using a calcium alginate beads impregnated with NiO/activated carbon: Preparation, characterization and RSM optimization. International Journal of Biological Macromolecules, 233, 123582, 2023. https://doi.org/10.1016/j.ijbi... PMid:36764345.
24.
OFGEA N.M., TURA A.M., FANTA G.M. Activated carbon from H3PO4-activated Moringa Stenopetale Seed Husk for removal of methylene blue: Optimization using the response surface method (RSM). Environmental and Sustainability Indicators, 16, 100214, 2022. https://doi.org/10.1016/j.indi....
25.
CHAN A.A., ABDUL RAMAN A.A., CHONG W.L., BUTHIYAPPAN A. Graphene oxide impregnated activated carbon derived from coconut shell through hydrothermal carbonization for cationic dye removal. Journal of Cleaner Production, 437, 140655, 2024. https://doi.org/10.1016/j.jcle....
26.
WANG Y., ZHANG Y., LI S., ZHONG W., WEI W. Enhanced methylene blue adsorption onto activated reed-derived biochar by tannic acid. Journal of Molecular Liquids, 268, 658, 2018. https://doi.org/10.1016/j.moll....
27.
LI Y., ZHANG Y., ZHANG Y., WANG G., LI S., HAN R., WEI W. Reed biochar supported hydroxyapatite nanocomposite: Characterization and reactivity for methylene blue removal. Journal of Molecular Liquids, 263, 53, 2018. https://doi.org/10.1016/j.moll....
28.
de OLIVEIRA T.F., de SOUZA C.P., LOPES-MORIYAMA A.L., PEREIRA DA SILVA M.L. In situ modification of MCM-41 using niobium and tantalum mixed oxide from columbite processing for methylene blue adsorption: Characterization, kinetic, isotherm, thermodynamic and mechanism study. Materials Chemistry and Physics, 294, 127011, 2023. https://doi.org/10.1016/j.matc....
29.
BAZAN-WOZNIAK A., NOSAL-WIERCIŃSKA A., YILMAZ S., PIETRZAK R. Chitin-based porous carbons from Hermetia illucens fly with large surface area for efficient adsorption of methylene blue; adsorption mechanism, kinetics and equilibrium studies. Measurement, 226, 114129, 2024. https://doi.org/10.1016/j.meas....
30.
DEIVASIGAMANI P., SENTHIL KUMAR P., SUNDARAMAN S., SOOSAI M.R., RENITA A.A., KARTHIKEYAN M., BEKTENOV N., BAIGENZHENOV O., VENKATESAN D., KUMAR J.A. Deep insights into kinetics, optimization and thermodynamic estimates of methylene blue adsorption from aqueous solution onto coffee husk (Coffee arabica) activated carbon. Environmental Research, 236, 116735, 2023. https://doi.org/10.1016/j.envr... PMid:37517489.
31.
JOSHIBA G.J., KUMAR P.S., RANGASAMY G., NGUEAGNI P.T., POOJA G., BALJI G.B., ALAGUMALAI K., EL-SEREHY H.A. Iron doped activated carbon for effective removal of tartrazine and methylene blue dye from the aquatic systems: Kinetics, isotherms, thermodynamics and desorption studies. Environmental Research, 215, 114317, 2022. https://doi.org/10.1016/j.envr... PMid:36174758.
32.
BOUCHELKIA N., TAHRAOUI H., AMRANE A., BELKACEMI H., BOLLINGER J., BOUZAZA A., ZOUKEL A., ZHANG J., MOUNI L. Jujube stones based highly efficient activated carbon for methylene blue adsorption: Kinetics and isotherms modeling, thermodynamics and mechanism study, optimization via response surface methodology and machine learning approaches. Process Safety and Environmental Protection, 170, 513, 2023. https://doi.org/10.1016/j.psep....
33.
AMRAN F., ZAINI M.A.A. Sodium hydroxide-activated Casuarina empty fruit: Isotherm, kinetics and thermodynamics of methylene blue and conго red adsorption. Environmental Technology & Innovation, 23, 101727, 2021. https://doi.org/10.1016/j.eti.....
34.
YAACOUBI F.E., SEKKOURI C., ENNACIRI K., RABICHI I., IZGHRI Z., BAÇAOUI A., YAACOUBI A. Synthesis of composites from activated carbon based on olive stones and sodium alginate for the removal of methylene blue. International Journal of Biological Macromolecules, 254, 127706, 2024. https://doi.org/10.1016/j.ijbi... PMid:37918596.
35.
ULFA M., PERTIWI Y.E., SARASWATI T.E., BAHRUJI H., HOLILAH H. Synthesis of iron triad metals-modified graphitic mesoporous carbon for methylene blue photodegradation. South African Journal of Chemical Engineering, 45, 149, 2023. https://doi.org/10.1016/j.sajc....
CITATIONS (5):
1.
Preparation and Adsorption Performance of Composite Activated Carbon from Organic Sludge and Biomass
Suqing Lu, Ang Wang, Yin Li, Yanqin Guo, Hanqiao Liu
Water, Air, & Soil Pollution
Suqing Lu, Ang Wang, Yin Li, Yanqin Guo, Hanqiao Liu
Water, Air, & Soil Pollution
2.
An Investigation of the Practicality, Effectiveness, and Thermodynamic Properties of Waste-Derived Adsorbents for the Removal of Methylene Blue
L. B. Almalike, A. A. Al-Asadi, A. S. Abdullah, R. Z. Homod, H. I. Mohammed
Russian Journal of Physical Chemistry B
L. B. Almalike, A. A. Al-Asadi, A. S. Abdullah, R. Z. Homod, H. I. Mohammed
Russian Journal of Physical Chemistry B
3.
Effect of biomass sources and synthesis methods on gas-phase chlorobenzene adsorption by biomass-derived magnetic activated carbons
Han-qiao Liu, Qian-long Han, Shujing Zhao, Guo-xia Wei, Yu-wen Zhu
Journal of Magnetism and Magnetic Materials
Han-qiao Liu, Qian-long Han, Shujing Zhao, Guo-xia Wei, Yu-wen Zhu
Journal of Magnetism and Magnetic Materials
4.
Polymer Crosslinked Activated Carbon Pellets for Dye Adsorption
Muhammad Hadi, Sungho Yoon
Materials
Muhammad Hadi, Sungho Yoon
Materials
5.
Lignin-Derived Hierarchical Porous Carbon for Efficient Methylene Blue Removal: Role of Fractionation, Surface Chemistry, and Charge Effects
Phuoc-Cuong Le, Dinh Nhi Bui, Xuan Kien Bui, Dinh Ngo Vu, Van Chau Dinh, Thi Thao Minh, Tan Nhat
Surfaces and Interfaces
Phuoc-Cuong Le, Dinh Nhi Bui, Xuan Kien Bui, Dinh Ngo Vu, Van Chau Dinh, Thi Thao Minh, Tan Nhat
Surfaces and Interfaces
Share
RELATED ARTICLE
| eISSN: | 2083-5906 |
| ISSN: | 1230-1485 |
We process personal data collected when visiting the website. The function of obtaining information about users and their behavior is carried out by voluntarily entered information in forms and saving cookies in end devices. Data, including cookies, are used to provide services, improve the user experience and to analyze the traffic in accordance with the Privacy policy. Data are also collected and processed by Google Analytics tool (more).
You can change cookies settings in your browser. Restricted use of cookies in the browser configuration may affect some functionalities of the website.
You can change cookies settings in your browser. Restricted use of cookies in the browser configuration may affect some functionalities of the website.
