ORIGINAL RESEARCH
An Innovative Geopolymer Composite Insulation Material Based on Phytoremediation Biowaste: Solidification/Stabilization of Potentially Toxic Metals
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1
Rocket Force University of Engineering, Xi’an, Shaanxi 710025, China
 
2
Xi’an Thermal Power Research Institute Co., Ltd., Xi’an, Shaanxi 710054, China
 
 
Submission date: 2025-07-06
 
 
Final revision date: 2025-08-15
 
 
Acceptance date: 2025-10-23
 
 
Online publication date: 2026-01-08
 
 
Corresponding author
Lei Zhang   

Xi’an Thermal Power Research Institute Co., Ltd., Xi’an, Shaanxi 710054, China
 
 
 
KEYWORDS
TOPICS
ABSTRACT
Phytoremediation biowaste without proper disposal might release potentially toxic metals (PTMs) back into the environment and pose a serious threat to environmental safety and human health. A composite geopolymer based on phytoremediation biowastes (PBWs) was used to effectively solidify/stabilize toxic heavy metals and served as an insulation material in the present study. For the solidification/stabilization of PTMs, the optimum proportion of biowastes in the geopolymer insulation material was 3%, at which the compressive strength of the geopolymer reached a maximum of 32.6 MPa and the thermal conductivity of the geopolymer was 0.11 W/(m·K), meeting the requirements of insulation materials. The leaching results indicated that the solidification efficiency of PTMs in the geopolymer materials was over 98%. The leaching concentration of all samples was within the standard limits and decreased with the extension of curing time. The XRD and FT-IR spectra of the biowaste-geopolymer confirmed the effective solidification/stabilization of PTMs in the geopolymer composite, where Zn was immobilized as carbonate and silicate. The geopolymer technique can stabilize the PTMs and prepare insulation materials simultaneously. Hence, this research provided a helpful insight and theoretical support for the post-treatment and the reutilization of plant waste accumulated with heavy metals.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
REFERENCES (60)
1.
DU J., ZHANG L., ALI A., LI R., XIAO R., GUO D., LIU X., ZHANG Z., REN C., ZHANG Z. Research on thermal disposal of phytoremediation biowaste: Stability of potentially toxic metals (PTMs) and oxidation resistance of biochars. Process Safety and Environment Protection. 125, 260, 2019. https://doi.org/10.1016/j.psep....
 
2.
KOVACS H., SZEMMELVEISZ K. Disposal options for polluted plants grown on heavy metal contaminated brownfield lands - a review. Chemosphere. 166, 8, 2017. https://doi.org/10.1016/j.chem....
 
3.
XIAO R., SHEN F., DU J., LI R., LAHORI A.H., ZHANG Z. Screening of native plants from wasteland surrounding a Zn smelter in Feng County China, for phytoremediation. Ecotoxicology and Environment Safety. 162, 178, 2018. https://doi.org/10.1016/j.ecoe....
 
4.
XU Z.Y., MUCHANGOS L.S., ITO L., TOKAI A. Cost and health benefit analysis of remediation alternatives for the heavy-metal-contaminated agricultural land in a Pb-Zn mining town in China. Journal Of Cleaner Production. 397, 2023. https://doi.org/10.1016/j.jcle....
 
5.
DASTYAR W., RAHEEM A., HE J., ZHAO M. Biofuel production using thermochemical conversion of heavy metal-contaminated biomass (HMCB) harvested from phytoextraction process. Chemical Engineering Journal. 358, 759, 2019. https://doi.org/10.1016/j.cej.....
 
6.
WANG S., GAO B., LI Y., OK Y.S., SHEN C., XUE S. Biochar provides a safe and value-added solution for hyperaccumulating plant disposal: a case study of Phytolacca acinosa Roxb. (Phytolaccaceae). Chemosphere. 178, 59, 2017. https://doi.org/10.1016/j.chem....
 
7.
SINGH J., KALAMDHAD A.S. Concentration and speciation of heavy metals during water hyacinth composting. Bioresource Technology. 124, 169, 2012. https://doi.org/10.1016/j.bior....
 
8.
BARBAROUX R., MEUNIER N., MERCIER G., TAILLARD V., MORE J.L., SIMONNOT M.O., BLAIS J.F. Chemical leaching of nickel from the seeds of the metal hyperaccumulator plant Alyssum murale. Hydrometallurgy. 100 (1-2), 10, 2009. https://doi.org/10.1016/j.hydr....
 
9.
NUNEZ-LOPEZ R.A., MEAS Y., GAMA S.C., BORGES R.O., OLGUIN E.J. Leaching of lead by ammonium salts and EDTA from Salvinia minima biomass produced during aquatic phytoremediation. Journal of Hazardous Materials. 154 (1-3), 623, 2008. https://doi.org/10.1016/j.jhaz....
 
10.
ZHONG D.X., ZHONG Z.P., WU L.H., DING K., LUO Y.M., CHRISTIE P. Pyrolysis of Sedum plumbizincicola, a zinc and cadmium hyperaccumulator: pyrolysis kinetics, heavy metal behaviour and bio-oil production. Clean Technologies and Environmental Policy. 18, 2315, 2016. https://doi.org/10.1007/s10098....
 
11.
JIANG H.W., CHEN X.F., CHEN S.K., LI H.G., PENG Y., ZHU A.G., XU C.B.C., YANG W.R. Recovery of arsenic and practical utilization of aqueous phase in hydrothermal liquefaction of hyperaccumulator. Chemical Engineering Journal. 439, 135514, 2022. https://doi.org/10.1016/j.cej.....
 
12.
SUI H.Q., JIANG H., LI G., CHEN J.F., CHENG W., CHEN H.P. Combustion of phytoremediation biomass for recycling utilization: Thermal behavior, kinetic analysis, and release of heavy metal. Industrial Crops & Products. 230, 121047, 2025. https://doi.org/10.1016/j.indc....
 
13.
DU J., ZHANG L., LIU T., XIAO R., LI R., GUO D., QIU L., YANG X., ZHANG Z. Thermal conversion of a promising phytoremediation plant (Symphytum officinale L.) into biochar: Dynamic of potentially toxic elements and environmental acceptability assessment of the biochar. Bioresource Technology. 274, 73, 2019. https://doi.org/10.1016/j.bior....
 
14.
HUANG H., YAO W., LI R., ALI A., DU J., GUO D., XIAO R., GUO Z., ZHANG Z., AWASTHI M.K. Effect of pyrolysis temperature on chemical form, behavior and environmental risk of Zn, Pb and Cd in biochar produced from phytoremediation residue. Bioresource Technology. 249, 487, 2018. https://doi.org/10.1016/j.bior....
 
15.
LI S., CHEN G. Thermogravimetric, thermochemical, and infrared spectral characterization of feedstocks and biochar derived at different pyrolysis temperatures. Waste Management. 78, 198, 2018. https://doi.org/10.1016/j.wasm....
 
16.
O'CONNOR D., PENG T., ZHANG J., TSANG D.C.W., ALESSI D.S., SHEN Z., BOLAN N.S., HOU D. Biochar application for the remediation of heavy metal polluted land: a review of in situ field trials. Science of the Total Environment. 619-620, 815, 2018. https://doi.org/10.1016/j.scit....
 
17.
LI Z.Y., HUANG Y.J., ZHU Z.C., YU M.Z., CHENG H.Q., SHI H., XIAO Y.X., SONG H.K., ZUO W., ZHOU H.Y., WANG S. Attempts to obtain clean biochar from hyperaccumulator through pyrolysis: Removal of heavy metals and transformation of phosphorus. Journal of Hazardous Materials. 468, 133837, 2024. https://doi.org/10.1016/j.jhaz....
 
18.
FAN C., WANG B., AI H., QI Y., LIU Z. A comparative study on solidification/stabilization characteristics of coal fly ash-based geopolymer and Portland cement on heavy metals in MSWI fly ash. Journal Of Cleaner Production. 319, 2021. https://doi.org/10.1016/j.jcle....
 
19.
RASAKI S.A., ZHANG B.X., GUARECUCO R., THOMAS T., YANG M.H. Geopolymer for use in heavy metals adsorption, and advanced oxidative processes: a critical review. Journal Of Cleaner Production. 213, 42, 2019. https://doi.org/10.1016/j.jcle....
 
20.
WANG S.Y., LIU B., ZHANG Q., WEN Q., LU X.H., XIAO K., EKBERG C., ZHANG S.G. Application of geopolymers of treatment of industrial solid waste containing heavy metals: State of the art review. Journal Of Cleaner Production. 390, 2023. https://doi.org/10.1016/j.jcle....
 
21.
PU S.Y., SHEN Z.W., DUAN W., LANG L., LIU Y., XU B.M., YAO H.R., MEI G.X. Discussion on the applicability and mechanism of phosphate-based geopolymers used for cadmium and cadmium-lead heavy metals solidification/stabilization. Journal Of Environmental Chemical Engineering. 12, 2024. https://doi.org/10.1016/j.jece....
 
22.
DAVIDOVITS J. Geopolymers - inorganic polymeric new materials. Journal Of Thermal Analysis and Calorimetry. 37, 1633, 1991. https://doi.org/10.1007/BF0191....
 
23.
XIA M., MUHAMMAD F., ZENG L., LI S., HUANG X., JIAO B., SHIAU Y., LI D. Solidification/stabilization of lead-zinc smelting slag in composite based geopolymer. Journal Of Cleaner Production. 209, 1206, 2019. https://doi.org/10.1016/j.jcle....
 
24.
ZOU S., LI H., WANG S., JIANG R., ZOU J., ZHANG X., LIU L., ZHANG G. Experimental research on an innovative sawdust biomass-based insulation material for buildings. Journal Of Cleaner Production. 260, 2020. https://doi.org/10.1016/j.jcle....
 
25.
LIU J.R., DOH J.H., ONG DOMINIC E.L., DINH H.L., PODOLSKY Z., ZI G. Investigation on red mud and fly ash-based geopolymer: Quantification of reactive aluminosilicate and derivation of effective Si/Al molar ratio. Journal of Building Engineering. 71, 2023. https://doi.org/10.1016/j.jobe....
 
26.
CHEN C.L., LIU H., ZHANG Y., GU G.H., HU J.Y. Micro-assessment of heavy metal immobilization within alkali-activated copper tailings-slag geopolymer. Cement and Concrete Composites. 149, 105510, 2024. https://doi.org/10.1016/j.cemc....
 
27.
SUN M.Y., MA L.P., DAI Q.X., YANG J., XIE L.G., HU Y., DUAN L., YAN X., ZHOU G.Y., ZENG L.L., SHAO L., HU B., YAN Q.C. Preparation of functional geopolymers from municipal solid waste incineration fly ash: An approach combining experimental and computational simulation studies. Journal of Environmental Management. 355, 2024. https://doi.org/10.1016/j.jenv....
 
28.
LU X., GUO J.F., CHEN F., TIAN M.K. Synthesis of ternary geopolymers using prediction for effective solidification of mercury in tailings. Journal of Environmental Sciences. 147, 392, 2025. https://doi.org/10.1016/j.jes.....
 
29.
REN B., ZHAO Y.L., BAI H.Y., KANG S.C., ZHANG T.T., SONG S.X. Eco-friendly geopolymer prepared from solid wastes: A critical review. Chemosphere. 267, 128900, 2021. https://doi.org/10.1016/j.chem....
 
30.
FREIRE A.L., SILVA A.D.A., ROCC D.G.D., SALLA J.D.A.S., PERGHER S.B.C., RODRÍGUEZ-CASTELLÓN E., JOSÉ H.J., MOREIRA R.DA F.P.M. Synthesis and characterization of geopolymers based on phosphate mining tailings and its application for carbon dioxide and nitrogen adsorption. Ceramics International. 51, 8396, 2025. https://doi.org/10.1016/j.cera....
 
31.
SU L.J., LI S.Q., WU S.Y., LIANG B., ZHANG X.D. Preparation and heavy metal solidification mechanism of physically activated municipal solid waste incineration fly ash base geopolymer backfill. Process Safety and Environmental Protection. 201, 107522, 2025. https://doi.org/10.1016/j.psep....
 
32.
JI Z.H., SU L.Y., PEI Y.S. Synthesis and toxic metals (Cd, Pb, and Zn) immobilization properties of drinking water treatment residuals and metakaolin-based geopolymers. Materials Chemistry and Physics. 242, 2020. https://doi.org/10.1016/j.matc....
 
33.
CHEN Y.C., CHEN F.Y., ZHOU F., LU M., HOU H.B., LI J.P., LIU D.M., WANG T. Early solidification/stabilization mechanism of heavy metals (Pb, Cr and Zn) in shell coal gasification fly ash based geopolymer. Science of the Total Environment. 820, 2022. https://doi.org/10.1016/j.scit....
 
34.
ZHANG Y., LIU H., MA T., CHEN C.L., GU G.H., WANG J.H., SHANG X. Experimental assessment of utilizing copper tailings as alkali-activated materials and fine aggregates to prepare geopolymer composite. Construction and Building Materials. 408, 2023. https://doi.org/10.1016/j.conb....
 
35.
HAN Y.J., QI W.Y., PANG H.T., ZHAO Q.X., HUANG Y.L., ZHAO D.Z., ZHU W.H., ZHANG J.H. A novel coal gasification coarse slag-based geopolymer: Influences of physico-chemical coupling activation on its properties, microstructure, and hazardous material immobilization. Construction and Building Materials. 420, 2024. https://doi.org/10.1016/j.conb....
 
36.
DU J., GUO Z., LI R., ALI A., GUO D., LAHORI A.H., WANG P., LIU X., WANG X., ZHANG Z. Screening of Chinese mustard (Brassica juncea L.) cultivars for the phytoremediation of Cd and Zn based on the plant physiological mechanisms. Environmental Pollution. 261, 2020. https://doi.org/10.1016/j.envp....
 
37.
WANG Y., HAN F., MU J. Solidification/stabilization mechanism of Pb(II), Cd(II), Mn(II) and Cr(III) in fly ash based geopolymers. Construction and Building Materials. 160, 2018. https://doi.org/10.1016/j.conb....
 
38.
ZHANG H., JI Z., ZENG Y., PEI Y. Solidification/stabilization of landfill leachate concentrate contaminants using solid alkali-activated geopolymers with a high liquid solid ratio and fixing rate. Chemosphere. 288, 2022. https://doi.org/10.1016/j.chem....
 
39.
ZHANG Q., CAO X., SUN S., YANG W., FANG L., MA R., LIN C., LI H. Lead zinc slag-based geopolymer: Demonstration of heavy metal solidification mechanism from the new perspectives of electronegativity and ion potential. Environmental Pollution. 293, 2022. https://doi.org/10.1016/j.envp....
 
40.
Thermal insulation-Determination of steady-state thermal resistance and related properties-Guarded hot plate apparatus (ISO 8302:1991, IDT; GB/T10294-2008, China). 1991.
 
41.
US Environmental Protection Agency. Method 1311: Toxicity Characteristic Leaching Procedure. Washington, DC, 1992.
 
42.
US Environmental Protection Agency. Method 1312: Synthetic precipitation leaching procedure. Washington, DC, 1992.
 
43.
PRC Ministry of Ecology and Environment. Identification Standards for Hazardous Wastes-Identification for Extraction Toxicity (GB5085.3-2007), Beijing, China, 2007.
 
44.
BAH A., JIN J., RAMOS A.O., BAO Y., MA M., LI F. Arsenic(V) immobilization in fly ash and mine tailing-based geopolymers: Performance and mechanism insight. Chemosphere. 306, 2022. https://doi.org/10.1016/j.chem....
 
45.
ZHAO S., XIA M., YU L., HUANG X., JIAO B., LI D. Optimization for the preparation of composite geopolymer using response surface methodology and its application in lead-zinc tailings solidification. Construction and Building Materials. 266, 2021. https://doi.org/10.1016/j.conb....
 
46.
US Environmental Protection Agency. Method 3051A: Microwave Assisted Acid Digestion of Soils. Washington, DC, 1992.
 
47.
ZHENG Y.H., WANG Z., WAN Z.M., YANG X., LIN F.C., CHEN Y.D., TANG L.R., LIN G.F., LU Q.L., HANG B., LU B.L. Mechanochemical fabrication of geopolymer composites based on the reinforcement effect of microfibrillated cellulose. Ceramics International. 49, 503, 2023. https://doi.org/10.1016/j.cera....
 
48.
YE H., ZHANG Y., YU Z., MU J. Effects of cellulose, hemicellulose, and lignin on the morphology and mechanical properties of metakaolin-based geopolymer. Construction and Building Materials. 173, 10, 2018. https://doi.org/10.1016/j.conb....
 
49.
LIU L., ZOU S., LI H., DENG L., BAI C., ZHANG X., WANG S., LI N. Experimental physical properties of an eco-friendly bio-insulation material based on wheat straw for buildings. Energy and Buildings. 201, 19, 2019. https://doi.org/10.1016/j.enbu....
 
50.
WANG S. Experimental study on preparation of building insulation materials by rice husk and geopolymer composite. Dissertation, Hunan University, China, 2018 [In Chinese].
 
51.
CN-GB. Dry-mixed thermal insulating composition for buildings (GB/T 20473-2006), Beijing, China, 2006.
 
52.
WANG S., LI H., ZOU S., LIU L., BAI C., ZHANG G., FANG L. Experimental study on durability and acoustic absorption performance of biomass geopolymer-based insulation materials. Construction and Building Materials. 361, 2022. https://doi.org/10.1016/j.conb....
 
53.
CHIU A.C.F., AKESSEH R., MOUMOUNI I.M., XIAO Y. Laboratory assessment of rice husk ash (RHA) in the solidification/stabilization of heavy metal contaminated slurry. Journal of Hazardous Materials. 371, 62, 2019. https://doi.org/10.1016/j.jhaz....
 
54.
AN S., WANG B.M., CHEN W.X., YU Z., FAN C.C. Preparation of geopolymer based on municipal solid waste incineration fly ash-phosphorus slag and its function for solidification of heavy metals. Waste Management. 178, 186, 2024. https://doi.org/10.1016/j.wasm....
 
55.
EL-ESWED B.I., ALDAGAG O.M., KHALILI F.I. Efficiency and mechanism of stabilization/solidification of Pb(II), Cd(II), Cu(II), Th(IV) and U(VI) in metakaolin based geopolymers. Applied Clay Science. 140, 148, 2017. https://doi.org/10.1016/j.clay....
 
56.
CAO L.Q., ZUO Y.B., LIANG S., SUN Y.F., KE Y., YANG J.K., WEI X.S., HU J.P., HOU H.J. Geopolymerization of MSWI fly ash and coal fly ash for efficient solidification of heavy metals: Insights into stabilization mechanisms and long-term leaching behavior. Construction and Building Materials. 411, 2024. https://doi.org/10.1016/j.conb....
 
57.
WAN Q., RAO F., SONG S., ZHANG Y. Immobilization forms of ZnO in the solidification/stabilization (S/S) of a zinc mine tailing through geopolymerization. Journal of Materials Research and Technology. 8 (6), 5728, 2019. https://doi.org/10.1016/j.jmrt....
 
58.
KARTHIK A., SUDALAIMANI K., VIJAYAKUMAR C.T., SARAVANAKUMAR S.S. Effect of bio-additives on physico-chemical properties of fly ash-ground granulated blast furnace slag based self-cured geopolymer mortars. Journal of Hazardous Materials. 361, 56, 2019. https://doi.org/10.1016/j.jhaz....
 
59.
LONG W.J., LIN C., YE T.H., DONG B., XING F. Stabilization/solidification of hazardous lead glass by geopolymers. Construction and Building Materials. 294, 2021. https://doi.org/10.1016/j.conb....
 
60.
ZAWRAH M.F., GADO R.A., FELTIN N., DUCOURTIEUX S., DEVOILLE L. Recycling and utilization assessment of waste fired clay bricks (grog) with granulated blast-furnace slag for geopolymer production. Process Safety and Environmental Protection. 103, 237, 2016. https://doi.org/10.1016/j.psep....
 
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