ORIGINAL RESEARCH
Comparison of Hydrochemical Characteristics of Groundwater in the Qihe River Alluvial Fan of North China over the Past 35 Years
Chao Bian 1,2
,
 
,
 
,
 
,
 
,
 
 
 
More details
Hide details
1
Hebei Province Collaborative Innovation Center for Sustainable Utilization of Water Resources and Optimization of Industrial Structure, Hebei GEO University, Shijiazhuang 050031, China
 
2
Center for Hydrogeology and Environmental Geology Survey, China Geological Survey, Tianjin 300309, China
 
3
State Key Laboratory of Biogeography and Environmental Geology, Wuhan 430078, China
 
4
The Prevent and Control Center for the Geological Disaster of Henan Geological Bureau, Zhengzhou 450000, China
 
 
Submission date: 2026-03-25
 
 
Final revision date: 2026-06-12
 
 
Acceptance date: 2026-08-12
 
 
Online publication date: 2026-11-03
 
 
Corresponding author
Huaisheng Zhang   

School of Water Resources and Environment, Hebei Province Collaborative Innovation Center for Sustainable Utilization of Water Resources and Optimization of Industrial Structure, Hebei GEO University, No. 136 Huai’an East Road, Yuhua District, 050031, Shijiazhuang, China
 
 
Yonggao Lyu   

Center for Hydrogeology and Environmental Geology Survey, China Geological Survey, Tianjin 300309, China
 
 
 
KEYWORDS
TOPICS
ABSTRACT
Groundwater resources play a crucial role in socioeconomic development and domestic water use in piedmont alluvial plain areas. In this study, the Qihe River alluvial fan (QRAF) was selected as a representative area to investigate the evolutionary patterns of shallow groundwater chemistry in the North China Plain (NCP). Based on shallow groundwater monitoring data collected during the wet seasons of 1983 and 2017, the spatiotemporal trends in chemical characteristics and their influencing factors in shallow groundwater in the QRAF were studied using multi-hydrochemical and statistical methods. The results showed that the groundwater in the QRAF was generally weakly alkaline, and groundwater quality has generally deteriorated over time. In particular, the concentrations of Cl‒ and NO3‒, two important indicators of water quality and pollution, increased significantly in 2017 compared with 1983. Although the groundwater chemical types were still dominated by HCO3-Ca and HCO3-Ca·Mg types, significant changes occurred along the middle to outer edge of the fan between 1983 and 2017, especially in the low-lying areas along the Weihe River. In 1983, the groundwater chemical composition was primarily controlled by natural processes such as water-rock interaction, whereas in 2017 it was additionally affected by anthropogenic activities, resulting in a more complex hydrochemical driving mechanism. The research findings can provide a reference for groundwater safety and protection management in the QRAF and other similar areas in the world.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
REFERENCES (58)
1.
ROHDE M.M., ALBANO C.M., HUGGINS X., KLAUSMEYER K.R., MORTON C., SHARMAN A., ZAVERI E., SAITO L., FREED Z., HOWARD J.K., JOB N., RICHTER H., TODERICH K., RODELLA A.-S., GLEESON T., HUNTINGTON J., CHANDANPURKAR H.A., PURDY A.J., FAMIGLIETTI J.S., SINGER M.B., ROBERTS D.A., CAYLOR K., STELLA J.C. Groundwater-dependent ecosystem map exposes global dryland protection needs. Nature, 632 (8023), 101, 2024.
 
2.
LAPWORTH D.J., BOVING T.B., KREAMER D.K., KEBEDE S., SMEDLEY P.L. Groundwater quality: Global threats, opportunities and realising the potential of groundwater. Science of The Total Environment, 811, 152471, 2022.
 
3.
GLEESON T., WADA Y., BIERKENS M.F.P., VAN BEEK L.P.H. Water balance of global aquifers revealed by groundwater footprint. Nature, 488 (7410), 197, 2012.
 
4.
SHARMA C., BAŞAĞAOĞLU H., YOOSEFDOOST I., WOOTTEN A., CHAKRABORTY-REDDY D., BERTETTI F.P., MIRCHI A., CHAKRABORTY D. Efficacy of mitigation strategies for aquifer sustainability under climate change. Nature Sustainability, 8 (1), 44, 2024.
 
5.
KHODJA H.D., AICHOUR A., METAICHE M., FERHATI A. Hydrochemical Assessment of Albian Waters of Southern Algeria Using Water Quality Indices. Polish Journal of Environmental Studies, 34 (5), 5599, 2025.
 
6.
XIAO Y., LIU K., HAO Q., XIAO D., ZHU Y., YIN S., ZHANG Y. Hydrogeochemical insights into the signatures, genesis and sustainable perspective of nitrate enriched groundwater in the piedmont of Hutuo watershed, China. Catena, 212, 2022.
 
7.
ABDELBAKI H., BELKENDIL A., MAAZOUZI A., MEKKAOUI A. Assessment of hydrochemical properties of groundwater in the alluvial aquifer of the arid zone of the Igli Region, South-West of Algeria. Desalination and Water Treatment, 268, 153, 2022.
 
8.
HOU X., WANG W., WANG Z., MA Z., GUAN C., XI D., LI P., LI J., HUANG X. Hydrogeological processes and hydrochemical effects in the Manas river catchment, Northwest China, over the past 60 years. Journal of Hydrology, 614 (Part A), 2022.
 
9.
BARATHKUMAR S., SELLAMUTHU K.M., SATHIYABAMA K., MALATHI P., KUMARAPERUMAL R., DEVAGI P., PAZHANIVELAN S. Groundwater quality assessment in selected polluted hotspots of Tamil Nadu, India using geospatial and statistical approaches. Desalination and Water Treatment, 322, 101047, 2025.
 
10.
SIDAURUK P., PRASETIO R., SATRIO, PUJIINDIYATI E.R. Origin and recharge area determination of springs around a lake for sustainability of the lake. Journal of Human, Earth, and Future, 6 (1), 27, 2025.
 
11.
CHEN L., FENG Q. Geostatistical analysis of temporal and spatial variations in groundwater levels and quality in the Minqin oasis, Northwest China. Environmental Earth Sciences, 70 (3), 1367, 2013.
 
12.
WANG J., GE Z., XIA R., HE S., ZHAN S. Hydrogeochemistry and stable isotopes of water: Characteristics, influencing factors and sources in a semi-arid irrigated basin, Hetao Plain. Journal of Arid Environments, 227, 2025.
 
13.
ZHAO Z., GAO Z., LIU J., LUO Z., SUN H., WANG Y., LI F. Hydrochemical characterization and comprehensive water quality assessment of groundwater within the main stream area of Yishu River. Environmental Monitoring and Assessment, 196 (6), 2024.
 
14.
WANG Z., WANG Y., SHI M., JI W., LI R., WANG X. Coordinated analysis of groundwater spatiotemporal chemical characteristics, water quality, and potential human health risks with sustainable development in semi-arid regions. Environmental Geochemistry and Health, 46 (10), 370, 2024.
 
15.
HE B., HE J., ZENG Y., SUN J., PENG C., BI E. Coupling of multi-hydrochemical and statistical methods for identifying apparent background levels of major components and anthropogenic anomalous activities in shallow groundwater of the Liujiang Basin, China. Science of The Total Environment, 838, 155905, 2022.
 
16.
HAN D., CURRELL M.J., GUO H. Controls on distributions of sulphate, fluoride, and salinity in aquitard porewater from the North China Plain: Long-term implications for groundwater quality. Journal of Hydrology, 603, 126828, 2021.
 
17.
XING L., GUO H., ZHAN Y. Groundwater hydrochemical characteristics and processes along flow paths in the North China Plain. Journal of Asian Earth Sciences, 70-71, 250, 2013.
 
18.
LI C., GAO Z., CHEN H., WANG J., LIU J., LI C., TENG Y., LIU C., XU C. Hydrochemical analysis and quality assessment of groundwater in southeast North China Plain using hydrochemical, entropy-weight water quality index, and GIS techniques. Environmental Earth Sciences, 80 (16), 2021. https://doi.org/10.1007/s12665....
 
19.
GU X., XIAO Y., YIN S., PAN X., NIU Y., SHAO J., CUI Y., ZHANG Q., HAO Q. Natural and anthropogenic factors affecting the shallow groundwater quality in a typical irrigation area with reclaimed water, North China Plain. Environmental Monitoring & Assessment, 189 (10), 514, 2017.
 
20.
GUO X., WANG W., SHI J., CHEN Z., GUO J., WANG H., LIU W., MIAO Y. Hydrochemical evolution and hydrological zoning characteristics of a shallow groundwater system in Baiyangdian Wetland, North China Plain. Hydrological Processes, 38 (6), e15219, 2024.
 
21.
YANG Y., ZHANG Z., WANG Z., LIU H., SUN Z. Formation of high fluoride groundwater and associated health risks in the Cangzhou area of the North China Plain. Environmental Earth Sciences, 84 (4), 111, 2025.
 
22.
LIU J., TSUJIMURA M., ZHANG J., YI Z. Utilizing Stable Isotopes and Major Ions to Isolate the Recharge Regime of an Alluvial-Proluvial Fan Aquifer in the Piedmont Region of the South Taihang Mountains, North China Plain. Water Resources, 50 (6), 969, 2023.
 
23.
HUANG X.-Y., ZHANG D., ZHAO Z.-Q., LIU Y.-T., MENG H.-Q., ZOU S., MA B.-J., FENG Q.-Y. Determining hydrogeological and anthropogenic controls on N pollution in groundwater beneath piedmont alluvial fans using multi-isotope data. Journal of Geochemical Exploration, 229, 2021.
 
24.
ZHANG Q., WANG L., WANG H., ZHU X., WANG L. Spatio-Temporal Variation of Groundwater Quality and Source Apportionment Using Multivariate Statistical Techniques for the Hutuo River Alluvial-Pluvial Fan, China. International Journal of Environmental Research and Public Health, 17 (3), 1055, 2020.
 
25.
QIU Y., MA C., QIAN J., WANG X. Comparison of different groundwater vulnerability evaluation models of typical karst areas in north China: a case of Hebi City. Environmental Science and Pollution Research, 28 (24), 30821, 2021.
 
26.
LI P., WU J., QIAN H. Hydrogeochemistry and quality assessment of shallow groundwater in the southern part of the Yellow River alluvial plain (Zhongwei section), Northwest China. Earth Sciences Research Journal, 18 (1), 27, 2014.
 
27.
CHEN K., LIU Q., PENG W., LIU X. Source apportionment and natural background levels of major ions in shallow groundwater using multivariate statistical method: A case study in Huaibei Plain, China. Journal of Environmental Management, 301, 113806, 2022.
 
28.
LIU J., LOU K., GAO Z., TAN M. Hydrochemical insights on the signatures and genesis of water resources in a high-altitude city on the Qinghai-Xizang Plateau, South-west China. Frontiers of Environmental Science & Engineering, 18 (7), 2024.
 
29.
LIU J., GAO Z., FENG J., WANG M. Identification of the hydrochemical features, genesis, water quality and potential health hazards of groundwater in Dawen River Basin, North China. Ecological Indicators, 149, 110175, 2023. https://doi.org/10.1016/j.ecol....
 
30.
NIYAZI B. Groundwater assessment for sustainable development in the Wadi Al-Hamd Basin, Al-Madinah Al-Munawarah, KSA. Journal of African Earth Sciences, 215 (1), 105289, 2024.
 
31.
LI H., ZHANG W., WANG Y., ZHANG L., LI X., GENG H., LU Y. Chemical characteristics and evolution of groundwater in northeastern margin of the Tibetan Plateau, China. Environmental Geochemistry and Health, 47 (1), 11, 2024.
 
32.
RADHI N.A., AL-MADHHACHI A.-S.T., SACHIT D.E. Groundwater quality and irrigation suitability assessment using geochemical and GIS-based approaches in arid regions. Civil Engineering Journal, 11 (11), 4536, 2025.
 
33.
TANG R., DONG S., ZHANG M., ZHOU Z., ZHANG C., LI P., BAI M. Hydrochemical Characteristics and Water Quality of Shallow Groundwater in Desert Area of Kunyu City, Southern Margin of Tarim Basin, China. Water, 15 (8), 1563, 2023.
 
34.
GUO P., CHEN S., LUO X., HU K., LI B. Hydrochemical Controlling Factors and Spatial Distribution Characteristics of Shallow Groundwater in Agricultural Regions of Central-Eastern Henan Province, China. Water, 17 (19), 2815, 2025.
 
35.
GIBBS R.J. Mechanisms controlling world water chemistry. Science, 170 (3962), 1088, 1970.
 
36.
SUBRAMANIYAN A., BALAJI A., ANDIMUTHU R. Assessment of groundwater quality for drinking and irrigation in Dindigul district, southern India: Hydrochemical characterization and spatial analysis. Desalination and Water Treatment, 320, 2024.
 
37.
LU L., WANG Z., WANG Z., DENG L., ZOU S., FAN L., YANG Y. Chemical characteristics and water quality assessment of groundwater in the Dongjiang-Hanjiang River Basin, China. Journal of Environmental Chemical Engineering, 12 (6), 2024.
 
38.
DENG Y., LU Y., DU X., YE X., FENG J. Identifying spatial patterns and driving factors of anthropogenic impacts on the groundwater environment based on groundwater chemical kinetics. Journal of Cleaner Production, 486 (4), 144436, 2025.
 
39.
LI C., MEN B.-H., YIN S.-Y. Analysis of Groundwater Chemical Characteristics and Spatiotemporal Evolution Trends of Influencing Factors in Southern Beijing Plain. Frontiers in Environmental Science, 10, 2022.
 
40.
GAILLARDET J., DUPRÉ B., LOUVAT P., ALLÈGRE C.J. Global silicate weathering and CO2 consumption rates deduced from the chemistry of large rivers. Chemical Geology, 159 (1-4), 3, 1999.
 
41.
AN R., LIU J., GAO Z., LI C., PENG Y. Hydrochemical Characterization, Controlling Factors and Water Quality of Surface Water in Shandong Province, North China. Journal of Earth Science, 35 (1), 155, 2024.
 
42.
ABDELAZIZ S., KHEIMI M., EIZELDIN M.A.H., SAFI AHMED H. A comparative study of PCA and KPCA for groundwater quality index estimation. Civil Engineering Journal, 11 (11), 4453, 2025.
 
43.
FU C., LI X., CHENG X., LIU C., BAI Z., LI J. Hydrochemical processes and water balance trends based on stable isotopes of typical alpine lakes in the Qinghai-Tibet Plateau. Journal of Geochemical Exploration, 270, 2025.
 
44.
WU Z., WU Y., YU Y., WANG L., QI P., SUN Y., FU Q., ZHANG G. Assessment of groundwater quality variation characteristics and influencing factors in an intensified agricultural area: An integrated hydrochemical and machine learning approach. Journal of Environmental Management, 371, 123233, 2024.
 
45.
GUO Y., ZHANG C., XIAO Q., BU H. Hydrogeochemical characteristics of a closed karst groundwater basin in North China. Journal of Radioanalytical and Nuclear Chemistry, 325 (2), 365, 2020.
 
46.
JU Q., HU Y., LIU Q., CHEN K. Spatial and Temporal Evolutions of Shallow Groundwater with Anthropogenic Activities: A Case Study of Sunan Mine Region, China. Polish Journal of Environmental Studies, 33 (3), 2715, 2024.
 
47.
ZHANG T., WANG P., HE J., LIU D., WANG M., WANG M., XIA S. Hydrochemical Characteristics, Water Quality, and Evolution of Groundwater in Northeast China. Water, 15 (14), 2669, 2023.
 
48.
PAN X., SUN B., ZHANG S., LI G., TIAN Z., GUO Z., YU H., YANG Z. Ion sources and seasonal recharge characteristics of groundwater around Dali Lake in semi-arid region of Inner Mongolia Plateau, China. Journal of Geochemical Exploration, 269, 2025.
 
49.
LIU J., PENG Y., LI C., GAO Z., CHEN S. Characterization of the hydrochemistry of water resources of the Weibei Plain, Northern China, as well as an assessment of the risk of high groundwater nitrate levels to human health. Environmental Pollution, 268, 2021.
 
50.
XIAOTONG W., MENG C., YONG W., RENMAO Y., JINQIAN Y. Hydrogeochemical Characteristics and Evolution Processes of Multilayer Karst Aquifer in the Huayingshan Coalfield, Southwest China. Water Resources, 51 (4), 576, 2024.
 
51.
KRISHAN G., KUMAR M., RAO M.S., GARG R., YADAV B.K., KANSAL M.L., SINGH S., BRADLEY A., MUSTE M., SHARMA L.M. Integrated approach for the investigation of groundwater quality through hydrochemistry and water quality index (WQI). Urban Climate, 47, 2023.
 
52.
HAJ R.A., MERHEB M., HALWANI J., OUDDANE B. Baseline hydro-geochemical characteristics of groundwater in Abu Ali watershed (Northern Lebanon). Journal of Hydrology: Regional Studies, 57, 102135, 2025.
 
53.
YU Y., YAN B., TUO Y., ZHAN X., XIE X. Chemical evolution characteristics and influencing factors of groundwater in the saline and fresh water funnel area in Hengshui City, North China. Scientific Reports, 15 (1), 2025.
 
54.
GAO M., LI X., QIAN J., WANG Z., HOU X., GUI C., BAI Z., FU C., LI J., ZUO X. Hydrochemical Characteristics and Controlling Factors of Shallow and Deep Groundwater in the Heilongdong Spring Basin, Northern China. Sustainability, 15 (21), 15447, 2023.
 
55.
LIU J., LOU K., GAO Z., WANG Y., LI Q., TAN M. Comprehending hydrochemical fingerprint, spatial patterns, and driving forces of groundwater in a topical coastal plain of Northern China based on hydrochemical and isotopic evaluations. Journal of Cleaner Production, 461, 2024.
 
56.
ZHANG M.-H., ZHOU S.-Y., LIU D.-D., ZHANG Y., ZHANG Y.-X., CHEN X., WANG H.-W., LI B., KANG W., YI B., SHI W.-P. Characteristics and genesis of groundwater salinization in coastal areas of the Lower Reaches of Oujiang Basin. Journal of Groundwater Science and Engineering, 12 (2), 190, 2024.
 
57.
XIA Y., LI Y., ZHANG X., YAN X. Nitrate source apportionment using a combined dual isotope, chemical and bacterial property, and Bayesian model approach in river systems. Journal of Geophysical Research: Biogeosciences, 122 (1), 2, 2017.
 
58.
SU C., LIU Y., CHENG Z., WANG W., ZHENG Z. Hydrochemical process and controls on the hydrochemistry of river water in the Muling-Xingkai Plain, Northeast China. Frontiers in Environmental Science, 10, 2022.
 
eISSN:2083-5906
ISSN:1230-1485
Journals System - logo
Scroll to top