Based on the two-stage innovation value chain model, incorporating environmental regulation policies and three-waste emissions into the research framework, constructing a green technology innovation efficiency evaluation index system from the perspectives of green inputs and outputs, and utilizing the super-efficiency SBM model and the Malmquist-Luenberger index model, assessing the effectiveness of green technological innovation in two aspects, namely, static, and dynamic, respectively. The results show that: the average value of green technical innovation efficiency of China's hightech industries is 0.5277, with significant differences between provinces, but the overall is constantly improving, showing an upward trend; the green technological innovation efficiency decreases from east to west, and the differences among the three major regions are not only embodied in spatial patterns, but also in the growth rate; during the period of investigation, the inefficient provinces are gradually decreasing, and the level of green technological innovation of China is constantly getting better; China's The average value of ML index of green technical innovation efficiency of high-tech industries in China is greater than 1, and the overall development trend is better; the increase of ML index in the eastern and central regions mainly relies on the positive influence of technological efficiency, while the decrease of ML index in the western part is affected by the recession of technological progress and technological efficiency, and the efficiency of technology research and development stage is generally higher than that of scientific and technical achievements transformation stage, and low efficiency of achievements transformation stage is mainly affected by the inhibiting effect of technological progress – inhibitory effect of technological advancement.