ORIGINAL RESEARCH
Characterization of Bottom Ashes
from Incineration of Different Compositions
of Municipal Solid Wastes: Implications
for its Valorization as a Cementitious Material
More details
Hide details
1
Laboratory of Plant Chemistry, Water and Energy, Faculty of Technology, Hassiba Ben Bouali University,
BP 151, Hay Essalem, 02000 Chlef, Algeria
2
Laboratory of Water and Environment, Faculty of Technology, Hassiba Ben Bouali University,
BP 151, Hay Essalem, 02000 Chlef, Algeria
3
The Thematic Agency for Research in Science and Technology (TARST). Avenue Pasteur, ENSA Ex INA,
Belfort, B.P 62- Hacene Badi, El Harrach, 16000 Algiers, Algeria
4
Laboratory E2LIM, University of Limoges. 123 Street Albert Thomas, 87060 Limoges, France
Submission date: 2024-04-28
Final revision date: 2024-09-30
Acceptance date: 2024-11-14
Online publication date: 2025-01-27
Publication date: 2026-01-29
Corresponding author
Yamina Rezkallah
Laboratory of Plant Chemistry, Water and Energy, Faculty of Technology, Hassiba Ben Bouali University,
BP 151, Hay Essalem, 02000 Chlef, Algeria
Pol. J. Environ. Stud. 2026;35(1):253-264
KEYWORDS
TOPICS
ABSTRACT
Currently, in Chlef (Algeria), Municipal solid wastes (MSWs) are treated by landfill. This work
proposes the incineration of MSWs, with the bottom ash (BA) generated being used in cement
manufacturing. This treatment is a promising way to achieve a circular economy and reduce
the environmental impact of MSWs in Chlef and Algeria. This research focused on two major goals.
First, it studied the influence of the raw composition of MSWs incinerated on the characteristics of
BAs generated. Second, it investigated the recycling of BAs as supplementary cementitious material
(SCM). To achieve the above objectives, one tonne of MSWs and 500 kg of organic MSWs generated
in the City of Chlef (Algeria) were incinerated in a rotary kiln, and a part of the ordinary Portland cement
(OPC) was replaced by 0 wt%, 5 wt%, 10 wt%, and 20 wt% of the two types of the generated BAs.
The results show that the oxides and heavy metal contents were not similar in both BAs. The incorporation
of both BAs into cement results in an increase in water demand for normal consistency. The results
indicate that the soundness values of all the cement pastes are less than 10 mm. From the results, it
is important to mention that there was a delay in the initial setting time for cement prepared with BA
from the incineration of one tonne of MSW. Both BAs adversely affected strength at a replacement level
of 20 wt%. However, the results also show that both BAs are beneficial when used as SCMs at replacement levels of 5 wt% and 10 wt%, as the physical and mechanical properties of the blended
types of cement remain comparable to those of OPC.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
REFERENCES (52)
1.
ALOBAID F., AL-MALIKI W.A.K., LANZ T., HAAF M., BRACHTHÄUSER A., EPPLE B., ZORBACH I. Dynamic simulation of a municipal solid waste incinerator. Energy, 149, 230, 2018.
https://doi.org/10.1016/j.ener....
2.
AGENCY N.W. Report on the state of waste management in Algeria. Available online:
http://rapportDMA2.pdf (and.dz), 2020.
3.
NAIMA T.D. Valorization by composting of municipal solid waste from the municipality of Chlef, Algeria. Thesis, University of Limoges, 2013.
4.
SAIKIA N., KATO S., KOJIMA T. Production of cement clinkers from municipal solid waste incineration (MSWI) fly ash. Waste Management, 27 (9), 1178, 2007.
https://doi.org/10.1016/j.wasm... PMid:16920348.
6.
NITHIYA A., SAFFARZADEH A., SHIMAOKA T. Hydrogen gas generation from metal aluminum-water interaction in municipal solid waste incineration (MSWI) bottom ash. Waste Management, 73, 342, 2018.
https://doi.org/10.1016/j.wasm... PMid:28666630.
7.
REHMAN A.U., LEE S.-M., KIM J.-H. Use of municipal solid waste incineration ash in 3D printable concrete. Process Safety and Environmental Protection, 142, 219, 2020.
https://doi.org/10.1016/j.psep....
8.
XUAN D., TANG P., POON C.S. Limitations and quality upgrading techniques for utilization of MSW incineration bottom ash in engineering applications - A review. Construction and Building Materials, 190, 1091, 2018.
https://doi.org/10.1016/j.conb....
9.
AUBERT J.-E., HUSSON B., SARRAMONE N. Utilization of municipal solid waste incineration (MSWI) fly ash in blended cement: Part 1: Processing and characterization of MSWI fly ash. Journal of Hazardous Materials, 136 (3), 624, 2006.
https://doi.org/10.1016/j.jhaz... PMid:16442718.
10.
FORTEZA R., FAR M., SEGUI C., CERDÁ V. Characterization of bottom ash in municipal solid waste incinerators for its use in road base. Waste Management, 24 (9), 899, 2004.
https://doi.org/10.1016/j.wasm... PMid:15504667.
11.
LU Y., TIAN A., ZHANG J., ANG Y., SHI P., TANG Q., HUANG Y. Physical and chemical properties, pretreatment, and recycling of municipal solid waste incineration fly ash and bottom ash for highway engineering: A literature review. Advances in Civil Engineering, 2020, 1, 2020.
https://doi.org/10.1155/2020/8....
12.
FERREIRA C., RIBEIRO A., OTTOSEN L. Possible applications for municipal solid waste fly ash. Journal of Hazardous Materials, 96 (2-3), 201, 2003.
https://doi.org/10.1016/S0304-... PMid:12493209.
13.
LI Y.-M., WU X.-Q., WANG L.-J., LI R.-Q., HUANG T.-Y., WEN X.-Q. Comparative study on utilization of different types of municipal solid waste incineration bottom ash for clinker sintering. Journal of Material Cycles and Waste Management, 22, 1828, 2020.
https://doi.org/10.1007/s10163....
14.
MATOS A.M., SOUSA-COUTINHO J. Municipal solid waste incineration bottom ash recycling in concrete: Preliminary approach with Oporto wastes. Construction and Building Materials, 323, 126548, 2022.
https://doi.org/10.1016/j.conb....
15.
CLAVIER K.A., PARIS J.M., FERRARO C.C., BUENO E.T., TIBBETTS C.M., TOWNSEND T.G. Washed waste incineration bottom ash as a raw ingredient in cement production: Implications for lab-scale clinker behavior. Resources, Conservation and Recycling, 169, 105513, 2021.
https://doi.org/10.1016/j.resc....
16.
LAM C.H.K., BARFORD J.P., MCKAY G. Utilization of municipal solid waste incineration ash in Portland cement clinker. Clean Technologies and Environmental Policy, 13, 607, 2011.
https://doi.org/10.1007/s10098....
17.
LOGINOVA E., SCHOLLBACH K., PROSKURNIN M., BROUWERS H. Mechanical performance and microstructural properties of cement mortars containing MSWI BA as a minor additional constituent. Case Studies in Construction Materials, 18, e01701, 2023.
https://doi.org/10.1016/j.cscm....
18.
LI X.-G., LV Y., MA B.-G., CHEN Q.-B., YIN X.-B., JIAN S.-W. Utilization of municipal solid waste incineration bottom ash in blended cement. Journal of Cleaner Production, 32, 96, 2012.
https://doi.org/10.1016/j.jcle....
19.
YANG Z., JI R., LIU L., WANG X., ZHANG Z. Recycling of municipal solid waste incineration by-product for cement composites preparation. Construction and Building Materials, 162, 794, 2018.
https://doi.org/10.1016/j.conb....
20.
EN 197-1. Cement - Part 1: Composition, specifications and conformity criteria for common cements. European Committee for Standardization, Brussel, 2000.
21.
LOGINOVA E., SCHOLLBACH K., PROSKURNIN M., BROUWERS H. Municipal solid waste incineration bottom ash fines: Transformation into a minor additional constituent for cements. Resources, Conservation and Recycling, 166, 105354, 2021.
https://doi.org/10.1016/j.resc....
22.
TANG P., CHEN W., XUAN D., ZUO Y., POON C.S. Investigation of cementitious properties of different constituents in municipal solid waste incineration bottom ash as supplementary cementitious materials. Journal of Cleaner Production, 258, 120675, 2020.
https://doi.org/10.1016/j.jcle....
23.
MAGNUSON J.K., WEIKSNAR K.D., PATEL A.D., CLAVIER K.A., FERRARO C.C., TOWNSEND T.G. Processing municipal solid waste incineration bottom ash for integration into cement product manufacture. Resources, Conservation and Recycling, 198, 107139, 2023.
https://doi.org/10.1016/j.resc....
24.
CHEN Z., YANG E.-H. Early age hydration of blended cement with different size fractions of municipal solid waste incineration bottom ash. Construction and Building Materials, 156, 880, 2017.
https://doi.org/10.1016/j.conb....
25.
KUMAR V., GARG N. The chemical and physical origin of incineration ash reactivity in cementitious systems. Resources, Conservation and Recycling, 177, 106009, 2022.
https://doi.org/10.1016/j.resc....
26.
AHMED A.O., ETONIHU A.C., NWEZE N.O. Analysis of chemical compositions of Portland cement and limestone from four geopolitical zones of Nigeria. Journal of Minerals and Materials Characterization and Engineering, 10 (2), 113, 2022.
https://doi.org/10.4236/jmmce.....
27.
EN 196-2. Method of testing cement-Part 2: Chemical analysis of cement, 2013.
28.
EN 12457-4. Characterisation of waste. Leaching. Compliance test for leaching of granular waste materials and sludges. One stage batch test at a liquid to solid ratio of 10 l/kg for materials with particle size below 10 mm (without or with size reduction), 2002.
29.
EN 196-3. Methods of testing cement-Part 3: Determination of setting times and soundness, 2005.
30.
EN 196-1. Methods of testing cement-Part 1: Determination of strength, 2005.
31.
JOSEPH A.M., SNELLINGS R., VAN DEN HEEDE P., MATTHYS S., DE BELIE N. The use of municipal solid waste incineration ash in various building materials: a Belgian point of view. Materials, 11 (1), 141, 2018.
https://doi.org/10.3390/ma1101... PMid:29337887 PMCid:PMC5793639.
32.
YAN M., TIAN X., YU C., ZHOU Z., HANTOKO D., KANCHANATIP E., KHAN M.S. Influence of multi-temperature primary air on the characteristics of MSW combustion in a moving grate incinerator. Journal of Environmental Chemical Engineering, 9 (6), 106690, 2021.
https://doi.org/10.1016/j.jece....
33.
MALDONADO-ALAMEDA À., GIRO-PALOMA J., ALFOCEA-ROIG A., FORMOSA J., CHIMENOS J.M. Municipal solid waste incineration bottom ash as sole precursor in the alkali-activated binder formulation. Applied Sciences, 10 (12), 4129, 2020.
https://doi.org/10.3390/app101....
34.
NIKRAVAN M., RAMEZANIANPOUR A.A., MAKNOON R. Study on physiochemical properties and leaching behavior of residual ash fractions from a municipal solid waste incinerator (MSWI) plant. Journal of Environmental Management, 260, 110042, 2020.
https://doi.org/10.1016/j.jenv... PMid:31941624.
35.
SAIKIA N., MERTENS G., VAN BALEN K., ELSEN J., VAN GERVEN T., VANDECASTEELE C. Pre-treatment of municipal solid waste incineration (MSWI) bottom ash for utilisation in cement mortar. Construction and Building Materials, 96, 76, 2015.
https://doi.org/10.1016/j.conb....
36.
SHI D., WANG P., XU X., GU L., LI L., MA H., HU C. Effect of source-classified collection of municipal solid waste on heavy metals and pozzolanic properties of incineration residues. International Journal of Environmental Research, 12, 661, 2018.
https://doi.org/10.1007/s41742....
37.
CAPRAI V., GAUVIN F., SCHOLLBACH K., BROUWERS H. MSWI bottom ash as binder replacement in wood cement composites. Construction and Building Materials, 196, 672, 2019.
https://doi.org/10.1016/j.conb....
38.
TANG P., FLOREA M., SPIESZ P., BROUWERS H. Characteristics and application potential of municipal solid waste incineration (MSWI) bottom ashes from two waste-to-energy plants. Construction and Building Materials, 83, 77, 2015.
https://doi.org/10.1016/j.conb....
39.
AN J., KIM J., NAM B.H. Investigation on impacts of municipal solid waste incineration bottom ash on cement hydration. ACI Materials Journal, 114 (5), 2017.
https://doi.org/10.14359/51689... PMid:28626299 PMCid:PMC5470119.
40.
LE N.H., RAZAKAMANANTSOA A., NGUYEN M.-L., DAO P.-L., NGUYEN D.H. Evaluation of physicochemical and hydromechanical properties of MSWI bottom ash for road construction. Waste Management, 80, 168, 2018.
https://doi.org/10.1016/j.wasm... PMid:30454996.
41.
GONZALEZ M.L., BLANC D., DE BRAUER C. Multi-Analytical approach and geochemical modeling for mineral trace element speciation in MSWI bottom-ash. Waste and Biomass Valorization, 10, 547, 2019.
https://doi.org/10.1007/s12649....
42.
SMIDT E., BÖHM K., SCHWANNINGER M. The application of FT-IR spectroscopy in waste management. In Fourier Transforms-New Analytical Approaches and FTIR Strategies, IntechOpen, 405, 2011.
https://doi.org/10.5772/15998.
43.
SMIDT E., MEISSL K., TINTNER J., OTTNER F. Interferences of carbonate quantification in municipal solid waste incinerator bottom ash: evaluation of different methods. Environmental Chemistry Letters, 8, 217, 2010.
https://doi.org/10.1007/s10311....
44.
SMIDT E., MEISSL K., SCHWANNINGER M., LECHNER P. Classification of waste materials using Fourier transform infrared spectroscopy and soft independent modeling of class analogy. Waste Management, 28 (10), 1699, 2008.
https://doi.org/10.1016/j.wasm... PMid:17890074.
45.
HAN Y., WANG H., XU Y., CAO Y., GAO P., LIU R. Effect of additives on properties and microstructure of lightweight aggregates produced from MSWI bottom ash sludge. Journal of the Air & Waste Management Association, 71 (8), 1013, 2021.
https://doi.org/10.1080/109622... PMid:33900893.
46.
TIHAY V., GILLARD P. Pyrolysis gases released during the thermal decomposition of three Mediterranean species. Journal of Analytical and Applied Pyrolysis, 88 (2), 168, 2010.
https://doi.org/10.1016/j.jaap....
47.
ALLAWZI M., AL-HARAHSHEH M., ALLABOUN H. Characterization and leachability propensity of bottom ash from medical waste incineration. Water, Air, & Soil Pollution, 229, 1, 2018.
https://doi.org/10.1007/s11270....
48.
AKKARAPONGTRAKUL A., JULPHUNTHONG P., NOCHAIYA T. Setting time and microstructure of Portland cement-bottom ash-sugarcane bagasse ash pastes. Monatshefte für Chemie-Chemical Monthly, 148, 1355, 2017.
https://doi.org/10.1007/s00706....
49.
WEEKS C., HAND R.J., SHARP J.H. Retardation of cement hydration caused by heavy metals present in ISF slag used as aggregate. Cement and Concrete Composites, 30 (10), 970, 2008.
https://doi.org/10.1016/j.cemc....
50.
GUTSALENKO T., BOURDOT A., MONTOUILLOUT V., DARQUENNES A., WATTEZ T., FROUIN L., CHAOUCHE M. Impact of trace metals Zn, Cu, Cd and Ni on the reactivity of OPC and GGBS-based hydraulic binders at early age for sediment stabilization. Construction and Building Materials, 346, 128406, 2022.
https://doi.org/10.1016/j.conb....
51.
NIU M., LI G., WANG Y., LI Q., HAN L., SONG Z. Comparative study of immobilization and mechanical properties of sulfoaluminate cement and ordinary Portland cement with different heavy metals. Construction and Building Materials, 193, 332, 2018.
https://doi.org/10.1016/j.conb....
52.
CHENG Y., HUANG X. Application of municipal solid waste incineration bottom ash into engineered cementitious composites. International Journal of Pavement Research and Technology, 1, 2022.