About the Journal
In Memory of Professor Jerzy Radecki
Editorial Office
Editorial Board
Scope
Impact Factor
Indexed in...
Journal Impact Factor contributing items
Contact
Subscription
Current issue
Online first
Notes to Authors
Frequently Asked Questions
Editorial policies
PJOES Publication Policy Overview
PJOES Peer Review Policy
PJOES Research Ethics and Malpractice Policy
PJOES Plagiarism Policy
PJOES Conflict of Interest Policy
PJOES Open Access Policy
PJOES Instructions for Reviewers
Generative AI and AI-Assisted Technologies Policy
Archive
ORIGINAL RESEARCH
Study on N2O Catalytic Decomposition
over NiO-Mn2O3@SiO2 Catalyst
1
School of New Materials and Chemical Engineering, Tangshan University, Tangshan 063000, China
2
School of Artificial Intelligence, Tangshan University, Tangshan 063000, China
Submission date: 2024-09-12
Final revision date: 2024-10-29
Acceptance date: 2024-12-02
Online publication date: 2025-03-03
Publication date: 2026-01-30
Corresponding author
Yuanyang Zhang
School of New Materials and Chemical Engineering, Tangshan University, 063000, Tangshan, China
School of New Materials and Chemical Engineering, Tangshan University, 063000, Tangshan, China
Pol. J. Environ. Stud. 2026;35(1):977-985
KEYWORDS
TOPICS
ABSTRACT
A series of NiO/SiO2 catalysts with different NiO loadings were first prepared using the impregnation
method. The basic characterization of NiO/SiO2 samples was characterized by BET and XRD.
The performance of NiO/SiO2 on catalytic decomposition of N2O was evaluated in a fixed bed reactor,
which indicated that the best performance on catalytic decomposition of N2O was the sample when the
loading of NiO was 16.0 (wt%), NiO(16.0%)/SiO2. On this basis, a series of NiO(16.0%)-Mn2O3(x%)/SiO2
catalysts were prepared, respectively. The experimental results showed that when the loadings
of Mn2O3 was 6.0 (wt%), i.e., NiO(16.0%)-Mn2O3(6.0%)/SiO2, its performance on catalytic N2O
decomposition was the best. The NiO (16.0%)-Mn2O3(x%)/SiO2 samples were characterized by using
XRD and H2-TPR. The stability test in the laboratory fixed bed reactor lasted for 100 hours and showed
that the NiO(16.0%)-Mn2O3 (6.0%)/SiO22 catalyst had good stability for the N2O catalytic decomposition,
which provided the basis for further relative research.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
REFERENCES (43)
1.
ZHANG Y.Y., GUO Y.Q., LI N., FENG Y.Y. Research status and progress on N2 O abatement and recycling technique N2 O. Environmental Protection of Chemical Industry. 38 (1), 499, 2018.
2.
YUAN C.J. Nitrous Oxide: Laughing gas should not be laughed off. Huaxue Tongbao. 86 (2), 244, 2023.
3.
LI A Q., WANG P., ZHANG L.D., ZHAO H.Y., JIN M.M., LEI L.L. Effect of different skeleton structures on N2 O decomposition from ammonia-fueled engines using Fe-based zeolite catalysts. Fuel. 378, 132888, 2024. https://doi.org/10.1016/j.fuel....
4.
CHIPPERFIELD M.P., BEKKI S., DHOMSE S., HARRIS NEIL R.P., HASSLER B., HOSSAINI R., STEINBRECHT W., THIÉBLEMONT R., WEBER M. Detecting recovery of the stratospheric ozone layer. Nature. 549 (7671), 211, 2017. https://doi.org/10.1038/nature....
5.
ZHAO H.Y., WANG P., LI Z.L., AO C.C., ZHAO X.T., LIN H. Improved activity and significant O2 resistance of Cs doped Co3 O4 catalyst for N2 O decomposition. Journal of Environmental Chemical Engineering. 12 (5), 113907, 2024. https://doi.org/10.1016/j.jece....
6.
GONÇALVES C., NOGUEIRA M., OLIVEIRA A. Greenhouse gas (N2 O) emission from Portuguese estuaries. Conference: IMMR, International Meeting on Marine Research 2014, Peniche, Portugal. Frontiers in Marine Science. 2014.
7.
YANG F., MIAO Y.Q., YE A.Z., CUI Q., SUN Y.L., LUO H., HONG W.L., SUN F.H. Characterization of N2 O emission at the water-gas interface and influence of Lake Chaohu. Journal of Lake Science. 35 (6), 2000, 2023.
8.
HUANG Y.H., SHE D.L., SHI Z.Q., HU L., PAN Y.C. Effect of different soil salinities on N2 O emission: A meta-analysis. Environmental Science. 45 (4), 1, 2023.
9.
TANG H.B., LÜ X.H., LI F.S., ZHAO S.T. Characteristics of greenhouse gas emissions in global food system. Research of Environmental Sciences. 36 (11), 1, 2023.
10.
LIU J.X., WANG X.C., LI C.Q., WANG H., SONG Y.J. Research progresses of metal oxide catalysts for direct catalytic decomposition of nitrous oxide. Environmental Protection of Chemical Industry. 41 (3), 263, 2021.
11.
JIA G.W., YANG N., WU X.H. The situation and suggestions for the control of non-carbon dioxide greenhouse gas emissions in China. Environmental Impact Assessment. 45 (3), 1, 2023.
12.
ZHANG C.H., YAO X. Path analysis and development trend of greenhouse gas treatment in tail gas of adipic acid industrial production. Henan Chemical Industry. 39 (9), 12, 2022.
13.
WANG C.X., LI Y.K., LIU Y.C. Effect of modified biochar on the removal of nitrate with low concentration and N2 O emission from water by a screened denitrifying bacterium. China Environmental Science. https://doi.org/10.19674/j.cnk..., 2023.
14.
WENG J.Y., XU R.Z., YANG J., CHEN L.L., FANG F. Current status and prospects of nitrogen oxides reduction and resource utilization in wastewater treatment systems. Applied Chemical Industry. 52 (9), 2637, 2023.
15.
JIN D.X., LI S.F., PU R.J., HE Z.Y., JIANG G.Z., ZHANG F.J., LI G.Y., LU X.H., LI X.J., PU B.L. Method for recovering and purifying nitrous oxide from a gas mixture containing nitrous oxide. Chinese Patent 109476483A [P], 2019.
16.
MIAO M., ZHOU T., WANG T., LI C.R., ZHANG M., YANG H.R. Feasibility of using red mud as bed material for treating N2 O in fluidized bed combustion. Fuel. 379, 133068, 2025. https://doi.org/10.1016/j.fuel....
17.
LIU H., YANG S., MI J.X., SUN C.Z., CHEN J.J., LI J.H. 4d-2p-4f gradient orbital coupling enables tandem catalysis for simultaneous abatement of N2 O and CO on atomically dispersed Rh/CeO2 catalyst. Environmental Science & Technology. 58 (38), 17125, 2024. https://doi.org/10.1021/acs.es....
18.
ZHANG D.Z., ZHAO Z., ZHANG C.H., LIU Z.J., TIAN Y.F., ZHONG R.X., LI Z.G., LI X.Y., YAO X., SONG M.M., FENG X., ZHAO X.W., LIU W., ZHANG S.W., SU Y.H. A high-temperature decomposition device and method for industrial exhaust gas containing N2 O. Chinese Patent 114754363A [P], 2022.
19.
ZHAO F.L., ZENG J., XIAO R., QIU L., GUO W., CHEN H.H., CHANG H.Z. Selective catalytic reduction of N2 O by CO over lanthanum doped Fe-beta zeolite. China Environmental Science. 43 (3), 1044, 2023.
20.
MAUVEZIN M. Catalytic reduction of N2 O by NH3 in presence of oxygen using Fe-exchanged zeolites. Catalysis Letters. 62 (1), 41, 1999. https://doi.org/10.1023/A:1019....
21.
KAMEOKA S., SUZUKI T., YUZAKI K., TAKEDA T., TANAKA S. Selective catalytic reduction of N2 O with methane in the presence of excess oxygen over Fe-BEA zeolite. Chemical Communications. 9, 745, 2000. https://doi.org/10.1039/b00132....
22.
ZENG J., CHEN S.Y., FAN Z.H., WANG C., LI J. Simultaneous selective catalytic reduction of NO and N2 O by NH3 over Fe-zeolite catalysts. Industrial & Engineering Chemistry Research. 59 (44), 19500, 2020. https://doi.org/10.1021/acs.ie....
23.
SÁDOVSKÁ G., TABOR E., SAZAMA P., LHOTKA M., SOBALÍK Z. High temperature performance and stability of Fe-FER catalyst for N2 O decomposition. Catalysis Communications. 89, 133, 2017. https://doi.org/10.1016/j.catc....
24.
ZHANG Y.Y., GUO Y.Q., LI N., FENG Y.Y. Catalytic decomposition of N2 O over supported RuO2/MexOy (Me=La, Mg, Al) catalysts. Industrial Catalysis. 26 (7), 43, 2018.
25.
CHATZIIONA V.K., CONSTANTINOU B.K., SAVVA P.G., OLYMPIOU G.G., KAPNISIS K., ANAYIOTOS A., COSTA C.N. Regulating the catalytic properties of Pt/Al2 O3 through nanoscale inkjet printing. Catalysis Communications. 103, 69, 2018. https://doi.org/10.1016/j.catc....
26.
ZHANG Y.Y., GUO Y.Q., LI N., FENG Y.Y. The preparation of hydrotalcite-like composite metal oxides and investigation on N2 O catalytic decomposition. Environmental Pollution & Control. 41 (5), 510, 2019.
27.
CAMPA M.C., PIETROGIACOMI D., TUTI S.C., LEA R., OCCHIUZZI M. N2 O decomposition on CoOx, CuOx, FeOx or MnOx supported on ZrO2: The effect of zirconia doping with sulfates or K+ on catalytic activity. Applied Catalysis B: Environmental. 187 (15), 218, 2016. https://doi.org/10.1016/j.apca....
28.
YU H.B., WANG X.P. Apparent activation energies and reaction rates of N2 O decomposition via different routes over Co3 O4. Catalysis Communications. 106, 40, 2018. https://doi.org/10.1016/j.catc....
29.
SUN J.R., XIA L., LI J.Y., LI S.X., LIU X.G., WANG H., LI C.Q., SONG Y.J. Effect of crystallization temperature on catalytic performance of Co3 O4 catalysts in decomposition of N2 O. Modern Chemical Industry. 39 (4), 89, 2019.
30.
JIA R., DONG W.Y., ZHANG L., YU H.B., JIANG X., ZHANG H.Z., LI S.J., QU M.H. Catalytic decomposition of N2 O over Co3 O4/KIT-6 catalyst. Journal of Molecular Science. 39 (2), 154, 2023.
31.
WANG Y.F., WANG Y.T., WANG X.C., MA X.F., LI C.Q., WANG H., SONG Y.J. Study on catalytic decomposition of N2 O by SiO2 aerogel supported transition metal oxides. Modern Chemical Industry. 42 (9), 134, 2022.
32.
CUI Y., LIN Y.B. Preparation and properties study on magnetic nanosilicon dioxide. Journal of Changchun University of Science and Technology (Natural Science Edition). 39 (6), 53, 2016.
33.
ZHOU H., LV B.L., XU Y., WU D. Synthesis and electrochemical properties of NiO nanospindles. Materials Research Bulletin. 50, 399, 2014. https://doi.org/10.1016/j.mate....
34.
YANG P., WEI X.W., WANG J., YANG F., ZHENG X.Y. Research on oxidation mechanism and fabrication of nickel oxide nanowires via high temperature oxidation. Journal of Xihua University (Natural Science). 34 (3), 70, 2015.
35.
XIA H.Y., HU L., YAO Q.Z. Preparation and photocatalytic activity of Mn2 O3 microspheres. Journal of Inorganic Materials. 26 (3), 317, 2011. https://doi.org/10.3724/SP.J.1....
36.
LIN Y.L., WU F., XIE Z.J., GAO B., TANG M., LU Y.N., WANG Y.C., ZHANG S., LIU Y.H., LIU Y.H. High temperature crystallization synthesis Mn2 O3@MoS2 composite materials and their adsorption properties for Uranium. Journal of Nuclear and Radiochemistry. 44 (4), 457, 2022.
37.
ZHAO D., TAN J.S., JI Q.Q., ZHANG J.T., ZHAO X.S., GUO P.Z. Mn2 O3 nanomaterials: Facile synthesis and electrochemical properties. Chinese Journal of Inorganic Chemistry. 26 (5), 832, 2010.
38.
LIU L.J., LIU B., NAKAGAWA Y., LIU S.B., WANG L., YABUSHITA M., TOMISHIGE K. Recent progress on bimetallic catalysts for the production of fuels and chemicals from biomass and plastics by hydrodeoxygenation. Chinese Journal of Catalysis. 62 (7), 1, 2024. https://doi.org/10.1016/S1872-....
39.
ZHANG Y.Y. Catalytic decomposition of greenhouse gas N2 O - Investigation on preparation and performance of composite metal oxide catalysts [D]. East China University of Science and Technology. 2000.
40.
HUANG Q.X., WANG F., LIU Y., ZHANG B.Y., GUO F.Y., JIA Z.Q., WANG H., YANG T.X., WU H.T., REN F.Z., YI F.F. Recent progress of two-dimensional metal-base catalysts in urea oxidation reaction. Rare Metals. 43 (8), 3607, 2024. https://doi.org/10.1007/s12598....
41.
VASAVAN H.N., BADOLE M., SAXENA S., SRIHARI V., DAS A.K., GAMI P., DAGAR N., DESWAL S., KUMAR P., POSWAL H.K., KUMAR S. Identification of optimal composition with superior electrochemical properties along the zero Mn3+ line in Na0.75 (Mn-Al-Ni)O2 pseudo ternary system. Journal of Energy Chemistry. 96 (9), 206, 2024. https://doi.org/10.1016/j.jech....
42.
LIU Z., ZHOU Z., HE F., CHEN B., ZHAO Y., XU Q. Catalytic decomposition of N2 O over NiO-CeO2 mixed oxide catalyst. Catalyst Today. 293-294, 56, 2017. https://doi.org/10.1016/j.catt....
43.
FRANKEN T., PALKOVITS R. Investigation of potassium doped mixed spinels Cux Co3-x O4 as catalysts for an efficient N2 O decomposition in real reaction conditions. Applied Catalysis B: Environmental. 176-177, 298, 2015. https://doi.org/10.1016/j.apca....
| eISSN: | 2083-5906 |
| ISSN: | 1230-1485 |
We process personal data collected when visiting the website. The function of obtaining information about users and their behavior is carried out by voluntarily entered information in forms and saving cookies in end devices. Data, including cookies, are used to provide services, improve the user experience and to analyze the traffic in accordance with the Privacy policy. Data are also collected and processed by Google Analytics tool (more).
You can change cookies settings in your browser. Restricted use of cookies in the browser configuration may affect some functionalities of the website.
You can change cookies settings in your browser. Restricted use of cookies in the browser configuration may affect some functionalities of the website.
