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ORIGINAL RESEARCH
Synthesis and Phosphate Removal
of Ce/Mg-MOF-74
1
School of Chemistry and Resources Engineering, Honghe University, Mengzi 661100, P. R. China
2
School of Chemical Sciences & Technology, School of Materials and Energy, Institute of International Rivers and Ecosecurity,
Yunnan University, Kunming 650091, P. R. China
3
Institute of International Rivers and Eco-security, Yunnan University, Kunming 650091, P. R. China
Submission date: 2024-01-19
Final revision date: 2024-05-18
Acceptance date: 2024-06-21
Online publication date: 2024-11-07
Publication date: 2025-06-06
Corresponding author
Mengyang Huang
School of Chemistry and Resources Engineering, Honghe University, Mengzi 661100, P. R. China
School of Chemistry and Resources Engineering, Honghe University, Mengzi 661100, P. R. China
Jiaqiang Wang
School of Chemical Sciences & Technology, Kunming, 650091, PR China, School of Chemical Sciences & Technology, Kunming, 650091, PR China, China
School of Chemical Sciences & Technology, Kunming, 650091, PR China, School of Chemical Sciences & Technology, Kunming, 650091, PR China, China
Pol. J. Environ. Stud. 2025;34(4):4915-4925
KEYWORDS
TOPICS
ABSTRACT
In this work, Ce doped Mg-MOF-74 with different Ce/Mg molar ratios was synthesized
and characterized by X-ray diffraction, N2 adsorption-desorption, scanning electron microscopy (SEM),
and X-ray Photoelectron Spectroscopy (XPS). It was found that Ce/Mg-metal organic framework-74
(Ce/Mg-MOF-74) has an excellent capability to remove phosphate. The effects of different Ce/Mg
molar ratios, crystallization temperature, pH, contact time, and the initial concentration of phosphorous
solution on phosphate removal have been studied. Ce/Mg-MOF-74 with a Ce/Mg molar ratio of 1:2
achieved a maximum phosphate uptake capacity of 106.4 mg/g, which is much higher than that of Mg-
MOF-74 (64.2 mg/g), Fe/Mg-MOF-74 (51.36 mg/g), and Ce-MOF (41.2 mg/g). The effect of the Ce/Mg
molar ratio, crystallization temperature, initial concentrations of phosphate, contact time, and solution
pH, on the adsorption of phosphate by Ce/Mg-MOF-74 was investigated. In addition, Ce/Mg-MOF-74
could be reused without significant loss of its adsorption performance after five cycles.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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