ORIGINAL RESEARCH
The Neutralization of Used Sovtol in Electrical Transformers Based on Calcium Oxide and Assessment of the Carbon Footprint in the Gas Phase
 
More details
Hide details
1
Institute of Physics named after Academician J. Jeenbaev NAS of the Kyrgyz Republic, Bishkek KR
 
2
Kyrgyz State Technical University named after. I. Razzakov, Bishkek, KR
 
3
Kyrgyz-Turkish Manas University, Bishkek, KR
 
4
Institute if Chemistry and Phytotechnology NAS of the Kyrgyz Republic, Bishkek, KR
 
 
Submission date: 2024-10-02
 
 
Final revision date: 2024-12-04
 
 
Acceptance date: 2024-12-16
 
 
Online publication date: 2025-02-25
 
 
Publication date: 2026-01-30
 
 
Corresponding author
Kubat Kemelov   

Environmental engineering, Kyrgyz-Turkish Manas University, 56 Chyngyz Aitmatov avenue, 720044, Bishkek, Kyrgyzstan
 
 
Pol. J. Environ. Stud. 2026;35(1):1285-1293
 
KEYWORDS
TOPICS
ABSTRACT
The work studied the multicomponent Sovtol-calcium oxide system with the aim of converting toxic chlorine organic molecules into a salt form in the form of calcium chloride. Accordingly, thermodynamic modeling of the process of thermal decomposition of Sovtol (C12H5Cl5–0.9, C6H3Cl3–0.1) and calcium oxide was carried out at a maximum entropy of the system over a wide range of temperatures. The values of change in entropy, enthalpy, and the viscosity parameters of the system (dynamic viscosity, Prandtl number) were calculated. The concentration distributions of C, O, H, Cl, and Ca-containing components and charged particles in the gas phase were established, and, on their basis, the contents of carbon and chlorine fragments at 2893 K were calculated. Reduction of the anthropogenic chlorine load from the organic molecule in the gas phase was achieved by preparing a water-suspension fuel emulsion (comprising fuel oil and spent Sovtol) with calcium oxide as solid additives and combusting the mixture in medium- and small-capacity boiler units. Based on the chemical matrix of the initial Sovtol-calcium oxide system, an assessment of the carbon load in the gas phase was carried out.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
REFERENCES (40)
1.
KUKHARCHIK T.I., KAKAREKA S.V., TSYTIK P.V. Polychlorinated biphenyls in electrical equipment. Minsk: Minsk tipproekt, 28, 2003 [In Russian].
 
2.
DJUMAEV I.A., PECHENYUK O.I., ILYAZOV M.K. Management of polychlorinated biphenyls in the Kyrgyz Republic. Collection of articles, Bishkek, 256, 2011 [In Russian].
 
3.
KAKAREKA S.V., KUKHARCHIK T.I. Sources of persistent organic pollutants entering the environment: experience of identification and study. Nature, 22, 157, 2012 [In Russian].
 
4.
LIU J., TAN Y., SONG E., SONG Y. A critical review of polychlorinated biphenyls metabolism, metabolites, and their correlation with oxidative stress. Chemical Research in Toxicology, 33 (8), 2022, 2020. https://doi.org/10.1021/acs.ch... PMid:32677429.
 
5.
RAO U.M., FOFANA I., JAYA T., RODRIGUEZ-CELIS E.M., JALBERT J., PICHER P. Alternative dielectric fluids for transformer insulation system: Progress, challenges, and future prospects. IEEE Access, 7, 184552, 2019. https://doi.org/10.1109/ACCESS....
 
6.
DUPONT NOMEX, USA. Available online: https://www.matweb.com/search/... (01.12.2024), 2024.
 
7.
Materials "Trihal". Schneider Electric Company, France. Available online: https://www.se.com/il/en/produ... (01.12.2024), 2024.
 
8.
Dielectric Fluid | Liquid Cooling Solutions For Electrics. Acota, United Kingdom. Available online: https://www.acota.co.uk/applic... (01.12.2024), 2024.
 
9.
MIDEL ester transformer dielectric fluids. Available online: https://www.midel.com/midel-ra... (01.12.2024), 2024.
 
10.
TLHABOLOGO B.A., SAMIKANNU R., MOSALAOSI M. Alternative liquid dielectrics in power transformer insulation: a review. Indonesian Journal of Electrical Engineering and Computer Science, 23 (3), 1761, 2021. https://doi.org/10.11591/ijeec....
 
11.
KULIKOVA T.V., MAIOROVA A.V., ILYINYKH N.I., BYKOV V.A. Formation of chlorine-containing components during high-temperature heating of polychlorinated biphenyls. Industrial Journal Konversiya, 45, 74, 2008 [In Russian].
 
12.
MAIOROVA A.V., KULIKOVA T.V., SAFRONOV A.P., GORBUNOVA T.I., PERVOVA M.G., SHUNYAEV K.Y. Thermal Decomposition of Polychlorobiphenyls and Their Derivatives. Russian Journal of Applied Chemistry, 93, 1254, 2020 [In Russian]. https://doi.org/10.1134/S10704....
 
13.
SRIVASTVA U., MALHOTRA R.K., KAUSHIK S.C. Experimental investigation of convective heat transfer properties of synthetic fluid. Journal of Thermal Analysis and Calorimetry, 132, 709, 2018. https://doi.org/10.1007/s10973....
 
14.
SAMBAEVA D.A., MAIMEKOV T.Z., KEMELOV K.A., IZAKOV ZH.B., MOLDOBAEV M.B., SHAIKIEVA N.T., MAIMEKOV Z.K. Sovol pyrolysis and chlorine decontamination of organic molecules based on metal oxides. Ecology of Urbanized Territories, 3, 20, 2021 [In Russian].
 
15.
MESHALKIN V.P. Current Theoretical and Applied Research on Energy- and Resource-Saving Highly Reliable Chemical Process Systems Engineering. Theoretical Foundations of Chemical Engineering, 55 (4), 563, 2021. https://doi.org/10.1134/S00405....
 
16.
MAIOROVA A.V., SAFRONOV A.P., KULIKOVA T.V., GORBUNOVA T.I., PERVOVA M.G., SHUNYAEV K.Y. Synthesis and thermal decomposition of alkoxy-hydroxyderivatives of Sovol polychlorbiphenyls technical mixture. Journal of Material Cycles and Waste Management, 22, 1552, 2020. https://doi.org/10.1007/s10163....
 
17.
TIWARI R., AGRAWAL P.S., BELKHODE P.N., RUATPUIA J.V., ROKHUM S.L. Hazardous effects of waste transformer oil and its prevention: A review. Next Sustainability, 3, 100026, 2024. https://doi.org/10.1016/j.nxsu....
 
18.
MONTANO L., PIRONTI C., PINTO G., RICCIARDI M., BUONO A., BROGNA C., MOTTA O. Polychlorinated biphenyls (PCBs) in the environment: occupational and exposure events, effects on human health and fertility. Toxics, 10 (7), 365, 2022. https://doi.org/10.3390/toxics... PMid:35878270 PMCid:PMC9323099.
 
19.
WANG B., WU A., LI X., SUN C., SHEN Z., CHI Z. Progress in fundamental research on thermal desorption remediation of organic compound-contaminated soil. Waste Disposal and Sustainable Energy, 3, 83, 2021. https://doi.org/10.1007/s42768....
 
20.
IMASAKA Y., KATAYAMA Y., HARADA H., SIMION C., SIMION A.M., MITOMA Y. Dry dechlorination of polychlorinated biphenyls in contaminated soil using nano-sized composite of metallic Ca/CaO and its mechanism. Chemosphere, 311, 137197, 2023. https://doi.org/10.1016/j.chem... PMid:36356819.
 
21.
FAN G., LIU X., LI X., LIN C., HE M., OUYANG W. Mechanochemical treatment with CaO-activated PDS of HCB contaminated soils. Chemosphere, 257, 127207, 2020. https://doi.org/10.1016/j.chem... PMid:32505949.
 
22.
HASHMI M.Z., KALEEM M., FAROOQ U., SU X., CHAKRABORTY P., REHMAN S.U. Chemical remediation and advanced oxidation process of polychlorinated biphenyls in contaminated soils: a review. Environmental Science and Pollution Research, 29 (16), 22930, 2022. https://doi.org/10.1007/s11356... PMid:35064511.
 
23.
HUANG C., ZENG Y., LUO X., REN Z., TIAN Y., MAI B. Comprehensive exploration of the ultraviolet degradation of polychlorinated biphenyls in different media. Science of the Total Environment, 755, 142590, 2021. https://doi.org/10.1016/j.scit... PMid:33059143.
 
24.
HU J., FENG Z., HUANG Z., YU J., LIU J. Mechanochemical destruction of 4-Bromochlorobenzene with CaO: Efficiency, kinetics, and mechanism. Environment Protection Engineering, 46 (2), 63, 2020. https://doi.org/10.37190/epe20....
 
25.
ZHANG Z., ZHOU Z., LIU X., ZHANG H., XU H., LIN C., OUYANG W. Mechanochemical remediation of lindane-contaminated soils assisted by CaO: Performance, mechanism and overall assessment. Journal of Hazardous Materials, 458, 131985, 2023. https://doi.org/10.1016/j.jhaz... PMid:37413802.
 
26.
WANG X., LV J., YING Y., MA Y., WU A., LIN X., YAN J. A new insight into the CaO-induced inhibition pathways on PCDD/F formation: Metal passivation, dechlorination and hydroxide substitution. Science of the Total Environment, 885, 163782, 2023. https://doi.org/10.1016/j.scit... PMid:37149162.
 
27.
MAYMEKOV Z.K., SAMBAEVA D.A., IZAKOV Z.B., KEMELOV K.A., MOLDOBAEV M.B. Destruction of environment: magnesium oxide-water-oxygen. Problemy Regionalnoj Ekologii, (4), 88, 2017 [In Russian].
 
28.
RYZHENKO N.O., BONDAR O.I., CHETVERYKOV V.V., FEDORENKO Y.O. Polychlorinated biphenyls: Hazardous properties and environmentally sound management in Ukraine. Regulatory Mechanisms in Biosystems, 11 (1), 37, 2020 [In Russian]. https://doi.org/10.15421/02200....
 
29.
WU C., AWASTHI A.K., QIN W., LIU W., YANG C. Recycling value materials from waste PCBs focusing on electronic components: technologies, obstruction and prospects. Journal of Environmental Chemical Engineering, 10 (5), 108516, 2022. https://doi.org/10.1016/j.jece....
 
30.
ZHU M., YUAN Y., YIN H., GUO Z., WEI X., QI X., DANG Z. Environmental contamination and human exposure of polychlorinated biphenyls (PCBs) in China: A review. Science of the Total Environment, 805, 150270, 2022. https://doi.org/10.1016/j.scit... PMid:34536863.
 
31.
VELAZCO M.Z., PEDROSO P.G., RAMOS G.V., VAN LANGENHOVE H. Chemical dechlorination for treatment of PCBs present in transformer oil (Sovtol-10): parameter study. Afinidad, 70 (563), 2013.
 
32.
LIU Z.K. Computational thermodynamics and its applications. Acta Materialia, 200, 745, 2020. https://doi.org/10.1016/j.acta....
 
33.
BELOV G.V., TRUSOV B.G. Thermodynamic modeling of chemically reacting systems. Moscow State Technical University Named After N.E. Bauman, Moscow, pp. 154, 2013 [In Russian].
 
34.
MAIMEKOV Z.K. Decomposition of spent polychlorinated biphenyls in a gas-liquid medium with barium, aluminum and calcium + magnesium oxides. Scientific project of the Ministry of Education and Science of the Kyrgyz Republic, state reg. No. 0007669, Bishkek, pp. 96, 2021 [In Russian].
 
35.
ZAITSAU D.H., EMELYANENKO V.N., PIMERZIN A.A., VEREVKIN S.P. Benchmark properties of biphenyl as a liquid organic hydrogen carrier: Evaluation of thermochemical data with complementary experimental and computational methods. The Journal of Chemical Thermodynamics, 122, 1, 2018. https://doi.org/10.1016/j.jct.....
 
36.
MAIMEKOV T.Z., SAMBAEVA D.A., MOLDOBAEV M.B., BAZHIROV T.S., MAIMEKOV Z.K. Forecasting and evaluating possibilities of carbon footprint during combustion of fuel oil in medium and low power boilers. Theoretical Foundations of Chemical Technology, 57 (5), 898, 2023. https://doi.org/10.1134/S00405....
 
37.
MAIMEKOV Z.K. Scientific basis for optimization of liquid fuel combustion processes and recarbonization of water-salt systems. Ministry of Education and Science of Kyrgyz Republic, Bishkek, pp. 410, 2015 [In Russian].
 
38.
On approval of methods for quantitative determination of greenhouse gas emissions and greenhouse gas absorption, 2022, Russian Federation. Available online: http://publication.pravo.gov.r... (01.12.2024), 2022.
 
39.
DUROJAYE O., LASEINDE T., OLUWAFEMI I. A descriptive review of carbon footprint. Advances in Intelligent Systems and Computing, in Human Systems Engineering and Design II, pp. 960, 2020. https://doi.org/10.1007/978-3-....
 
40.
BÖHRINGER C., FISCHER C., ROSENDAHL K.E., RUTHERFORD T.F. Potential impacts and challenges of border carbon adjustments. Nature Climate Change, 12 (1), 22, 2022. https://doi.org/10.1038/s41558....
 
eISSN:2083-5906
ISSN:1230-1485
Journals System - logo
Scroll to top